(triphenylphosphine)3(CO)nickelk

Base Information

• Chemical Name: (triphenylphosphine)3(CO)nickelk
• CAS No.: 15376-83-7
• Molecular Formula: C₅₅H₄₅NiOP₃
• Molecular Weight: 873.573
• Mol file: 15376-83-7.mol

Synonyms:(triphenylphosphine)3(CO)nickelk

Chemical Property of (triphenylphosphine)3(CO)nickelk

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (triphenylphosphine)3(CO)nickelk

There total 22 articles about (triphenylphosphine)3(CO)nickelk which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + benzyl formate (104-57-4) → (triphenylphosphine)3(CO)nickelk (15376-83-7) + benzaldehyde (100-52-7) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With triphenylphosphine; In diethyl ether; byproducts: 1,3-cyclooctadiene, 1,4-cyclooctadiene, bicyclooctene-1; ester added to Schlenk tube contg. Ni(cod)2, PPh3, and Et2O at room temp., stirred at 65°C for 4 h; cooled down to -30°C; GLC anal.;

DOI:10.1246/bcsj.55.623

Reference yield: 90.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + Propansaeure-(4-methoxyphenyl)ester (13098-94-7) → (triphenylphosphine)3(CO)nickelk (15376-83-7) + ethene (74-85-1) + phenol (108-95-2,27073-41-2)

Guidance literature:

With triphenylphosphine; In neat (no solvent); (N2 or Ar or vac.), EtCOOPh-OCH3 added to Ni(cod)2 and PPh3 (PPh3/Ni = 3), mixture stirred at 70°C for 8 h; GLC; Kinetics;

DOI:10.1021/ja00531a016

Reference yield: 80.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + phenyl propionate (637-27-4,132899-52-6) → (triphenylphosphine)3(CO)nickelk (15376-83-7) + ethene (74-85-1) + phenol (108-95-2,27073-41-2)

Guidance literature:

With triphenylphosphine; In neat (no solvent); byproducts: diethyl ketone, 1,3-cyclooctadiene, 1,4-cyclooctadiene; further byproducts: 1,5-cyclooctadiene, bicyclooctene-1, bicyclooctene-2, (N2 or Ar or vac.), EtCOOPh added to Ni(cod)2 and PPh3 (PPh3/Ni = 10), mixture stirred at 54°C for 21 h; gas chromy., volatile removed in vac., recrystd. from THF-hexane; Kinetics;

DOI:10.1021/ja00531a016

upstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

buta-1,3-diene

Phenyl acetate

propionic acid 4-cyanophenyl ester

Downstream raw materials:

Ni(CO)CH₃C{CH₂P(C₆H₅)2}3

Refernces

• 1、 Petz. "Reaction of C(NMe2)4 with Ni(CO)4 - syntheses and structures of [C(NMe2)3][(CO)3NiC(O)NMe2], [C(NMe2)3]2[Ni5(CO)12], and[C(". . p. 2274 - 2280. Retrieved 2008/10/08.
• 2、 Yamamoto, Takakazu,Ishizu, Junichi,Yamamoto, Akio. "Oxidative Addition of Esters of Formic Acid and β-Lactones to Ni(0)-Complexes Involving Cleavage of the C-O Bond". . p. 623 - 624. Retrieved 2007/10/02.