Technology Process of C42H54BrN3O11
There total 9 articles about C42H54BrN3O11 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C27H37IN2O8;
With
isopropylmagnesium chloride;
In
tetrahydrofuran;
at -30 ℃;
With
copper(I) bromide dimethylsulfide complex;
In
tetrahydrofuran;
at -30 - -20 ℃;
for 0.333333h;
(4R,2E)-3-(1-oxo-2-isohexenyl)-4-phenyl-2-oxazolidinone;
stereoselective reaction;
Further stages;
DOI:10.1021/ol902944f
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: dmap / acetonitrile
2.1: zinc; acetic acid / dichloromethane / 0.33 h / 0 - 20 °C
3.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.08 h / 0 °C
3.2: 1 h / 20 °C
4.1: isopropylmagnesium chloride / tetrahydrofuran / 0.5 h / -30 °C
4.2: 0.33 h / -30 - -20 °C
4.3: 8 h / -78 - 0 °C
With
hydrogenchloride; dmap; isopropylmagnesium chloride; acetic acid; zinc; sodium nitrite;
In
tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1016/j.tet.2014.05.082
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: triethylamine / tetrahydrofuran / 2 h / -20 °C
1.2: 4 h / -20 - 20 °C
2.1: isopropylmagnesium chloride / tetrahydrofuran / 0.5 h / -30 °C
2.2: 0.33 h / -30 - -20 °C
2.3: 8 h / -78 - 0 °C
With
isopropylmagnesium chloride; triethylamine;
In
tetrahydrofuran;
DOI:10.1016/j.tet.2014.05.082