N-ETHYLIDENE TERT-BUTYLAMINE

Base Information

• Chemical Name: N-ETHYLIDENE TERT-BUTYLAMINE
• CAS No.: 7020-80-6
• Molecular Formula: C6H13N
• Molecular Weight: 99.1759
• Hs Code.: 2921199090
• Mol file: 7020-80-6.mol

Synonyms:Ethylamine,N-ethylidene-1,1-dimethyl- (6CI,7CI,8CI);Acetaldehyde tert-butylimine;N-Ethylidene-tert-butylamine;N-tert-Butylacetaldimine;N-tert-Butylethylidenamine;N-[(1E)-ethylidene]-2-methylpropan-2-amine;2-Propanamine, N-[(1E)-ethylidene]-2-methyl-;Acetaldehyde tert-Butylimine;N-[(1E)-Ethylidene]-2-methylpropan-2-amine;N-Ethylidene tert-butylamine;t-Butylethylideneamine;

Chemical Property of N-ETHYLIDENE TERT-BUTYLAMINE

Chemical Property:

• Vapor Pressure: 17.3mmHg at 25°C
• Refractive Index: 1.403
• Boiling Point: 121.7 °C at 760 mmHg
• Flash Point: 18.4 °C
• PSA: 12.36000
• Density: 0.73 g/cm³
• LogP: 1.87560

Purity/Quality:

98%min ^*data from raw suppliers

N-Ethylidene-tert-butylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: N-Ethylidene-tert-butylamine can be used for general synthetic approach of natural products empowered by potentially biomimetic ring expansion.

Technology Process of N-ETHYLIDENE TERT-BUTYLAMINE

There total 4 articles about N-ETHYLIDENE TERT-BUTYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

acetaldehyde (75-07-0,9002-91-9) + tert-butylamine (75-64-9) → acetaldehyde N-tert-butylimine (7020-80-6)

Guidance literature:

acetaldehyde; tert-butylamine; at 0 ℃; for 3h; Inert atmosphere;

With potassium hydroxide; at 4 ℃; for 12h; Inert atmosphere;

Reference yield:

N-tert-Butyl-N-vinylcarbamidsaeurechlorid (28705-47-7) → acetaldehyde N-tert-butylimine (7020-80-6)

Guidance literature:

zinc; at 150 ℃;

DOI:10.1016/S0040-4020(01)90068-7

Reference yield:

rac-N2,N3-di-tert-butylbutane-2,3-diamido lead(II) → acetaldehyde N-tert-butylimine (7020-80-6)

Guidance literature:

at 150 ℃; for 6h; Schlenk technique;

DOI:10.1021/acs.inorgchem.8b00719

upstream raw materials:

acetaldehyde

tert-butylamine

N-tert-Butyl-N-vinylcarbamidsaeurechlorid

Downstream raw materials:

1-tert-butyl-4-methyl-1-aza-1,3-butadiene

(Z)-β-(4-methoxyphenyl)cinnamic aldehyde

(E)-β-(4-methoxyphenyl)cinnamic aldehyde

α-(Trimethylsilyl)-tert-butylacetaldimine

Refernces

• 1、 Ba?i?, Goran,Zanders, David,Mallick, Bert,Devi, Anjana,Barry, Seán T.. "Designing Stability into Thermally Reactive Plumbylenes". supporting information. p. 8218 - 8226. Retrieved 2018/07/25.
• 2、 -. "PROCESS FOR PRODUCING QUINOLINE COMPOUND". Page/Page column 6. . Retrieved 2008/06/13.