Phosphazenebase P2-F

Base Information

• Chemical Name: Phosphazenebase P2-F
• CAS No.: 137334-99-7
• Molecular Formula: C12H36FN7P2
• Molecular Weight: 359.411
• European Community (EC) Number: 621-415-9
• DSSTox Substance ID: DTXSID80449413
• Mol file: 137334-99-7.mol

Synonyms:Phosphazenebase P2-F;137334-99-7;1,1,1,3,3,3-HEXAKIS(DIMETHYLAMINO)DIPHOSPHAZENIUM FLUORIDE;tris(dimethylamino)-[[tris(dimethylamino)-lambda5-phosphanylidene]amino]phosphanium;fluoride;SCHEMBL4277898;DTXSID80449413;1,1,1,3,3,3-Hexakis(dimethylamino)-3lambda~5~-diphosphaz-2-en-1-ium fluoride

Chemical Property of Phosphazenebase P2-F

Chemical Property:

• Flash Point: -11 °C
• PSA: 55.20000
• LogP: -1.01620
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 7
• Exact Mass: 359.24914634
• Heavy Atom Count: 22
• Complexity: 293

Purity/Quality:

95% ^*data from raw suppliers

1,1,1,3,3,3-HEXAKIS(DIMETHYLAMINO)DIPHOSPHAZENIUM FLUORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,T
• Statements: 45-46-11-36/38-48/23/24/25-65-34
• Safety Statements: 53-36/37-45-62-36/37/39-26-16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)P(=N[P+](N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C.[F-]

Technology Process of Phosphazenebase P2-F

There total 2 articles about Phosphazenebase P2-F which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

dimethyl amine (124-40-3) → N,N,N,N,N,N-hexamethylphosphoric triamide (680-31-9) + C11H30N6P(1+) + 1,1,1,3,3,3-hexakis(dimethylamino)-1λ5,3λ5-diphosphazenium fluoride (137334-99-7)

Guidance literature:

Multistep reaction;

Reference yield: 90.0%

1,1,1,3,3,3-hexakis(dimethylamino)-1λ5,3λ5-diphosphazenium tetrafluoroborate → 1,1,1,3,3,3-hexakis(dimethylamino)-1λ5,3λ5-diphosphazenium fluoride (137334-99-7)

Guidance literature:

With potassium fluoride; In methanol; at 80 - 100 ℃; for 2h;

DOI:10.1002/chem.200500838

Reference yield:

{[1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene]gold(I)[η2-(3-hexyne)]}tetrafluoroborate + 1,1,1,3,3,3-hexakis(dimethylamino)-1λ5,3λ5-diphosphazenium fluoride (137334-99-7) → (1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene)gold(I) fluoride + ((((CH3)2CH)2C6H3)2CH2CH2N2C)Au((CH3CH2)2C2F)

Guidance literature:

In dichloromethane; treatment Au complex with ((Me2N)3P)2NF;

DOI:10.1021/ja0723784

upstream raw materials:

dimethyl amine

Refernces

• 1、 Schwesinger, Reinhard,Link, Reinhard,Wenzl, Peter,Kossek, Sebastian. "Anhydrous phosphazenium fluorides as sources for extremely reactive fluoride ions in solution". . p. 438 - 445. Retrieved 2008/09/19.