9-FLUOROANTHRACENE

Base Information

• Chemical Name: 9-FLUOROANTHRACENE
• CAS No.: 529-85-1
• Molecular Formula: C₁₄H₉F
• Molecular Weight: 196.224
• Hs Code.: 2903999090
• Mol file: 529-85-1.mol

Synonyms:9-FLUOROANTHRACENE

Chemical Property of 9-FLUOROANTHRACENE

Chemical Property:

• Vapor Pressure: 0.000165mmHg at 25°C
• Refractive Index: 1.69
• Boiling Point: 340.9 °C at 760 mmHg
• Flash Point: 129.7 °C
• PSA: 0.00000
• Density: 1.212 g/cm³
• LogP: 4.13210

Purity/Quality:

99%, ^*data from raw suppliers

9-FLUOROANTHRACENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-FLUOROANTHRACENE

There total 18 articles about 9-FLUOROANTHRACENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

9-(1-hydroxyethyl)anthracene (74928-67-9,94942-50-4,114128-93-7,7512-20-1) → 9-fluoroantracene (529-85-1)

Guidance literature:

With caesium fluoroxysulphate; In acetonitrile; for 1h; Ambient temperature;

DOI:10.1039/c39920000274

Reference yield: 58.0%

9-Bromoanthracene (1564-64-3) → 9-fluoroantracene (529-85-1)

Guidance literature:

9-Bromoanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 3h; Inert atmosphere;

With N-fluorobis(benzenesulfon)imide; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1002/anie.201610402

Reference yield: 36.0%

anthracene (120-12-7) → 9-fluoroantracene (529-85-1)

Guidance literature:

With tetrabutyl ammonium fluoride; In acetonitrile; electrolysis at 1.0 V vs. Ag/Ag⁺;

DOI:10.1021/jo00189a031

upstream raw materials:

9-Fluor-1,2,3,4,5,6,7,8-octahydroanthracen

9-hydroxymethylanthracene

9-(1-hydroxyethyl)anthracene

anthracene

Refernces

• 1、 Ghorbani, Fereshte,Harry, Stefan Andrew,Capilato, Joseph N.,Pitts, Cody Ross,Joram, Jacob,Peters, Garvin N.,Tovar, John D.,Smajlagic, Ivor,Siegler, Maxime A.,Dudding, Travis,Lectka, Thomas. "Carbonyl-Directed Aliphatic Fluorination: A Special Type of Hydrogen Atom Transfer Beats out Norrish II". . p. 14710 - 14724. Retrieved 2020/10/13.
• 2、 Laali, Kenneth K.,Tanaka, Mutsuo,Forohar, Farhad,Cheng, Michael,Fetzer, John C.. "Facile one-pot fluorination of polycyclic aromatic hydrocarbons (PAHs) with N-fluoro-2,4-dinitroimidazole; scope and limitation". . p. 185 - 190. Retrieved 2007/10/03.