METHYLTHIOMETHYL P-TOLYL SULFONE

Base Information

• Chemical Name: METHYLTHIOMETHYL P-TOLYL SULFONE
• CAS No.: 59662-65-6
• Molecular Formula: C9H12O2S2
• Molecular Weight: 216.325
• Hs Code.: 2930909090
• Mol file: 59662-65-6.mol

Synonyms:METHYLTHIOMETHYL P-TOLYL SULFONE;METHYL P-TOLUENESULFONYLMETHYL SULFIDE;METHYLMERCAPTOMETHYL P-TOLYL SULFONE;MT-SULFONE;Methylthiomethyltolylsulfone;METHYLTHIOMETHYL P-TOLYL SULPHONE

Chemical Property of METHYLTHIOMETHYL P-TOLYL SULFONE

Chemical Property:

• Vapor Pressure: 2.9E-05mmHg at 25°C
• Melting Point: 82-85 °C(lit.)
• Refractive Index: 1.559
• Boiling Point: 367.4°C at 760 mmHg
• Flash Point: 176°C
• PSA: 67.82000
• Density: 1.215g/cm³
• LogP: 3.17000

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methylthiomethyl p-tolyl sulfone ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYLTHIOMETHYL P-TOLYL SULFONE

There total 20 articles about METHYLTHIOMETHYL P-TOLYL SULFONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methanethiosulfonic acid S-methyl ester (2949-92-0,31761-75-8) + 1-phenyl-2-tosylethanone (31378-03-7) → methylthiomethyl p-tolyl sulfone (59662-65-6)

Guidance literature:

In ethanol; Heating;

DOI:10.1016/S0040-4020(01)90393-X

Reference yield: 85.0%

1-phenyl-2-tosylethanone (31378-03-7) + S-methyl p-chlorobenzenethiosulfonate (68305-26-0) → methylthiomethyl p-tolyl sulfone (59662-65-6)

Guidance literature:

In ethanol; Heating;

DOI:10.1016/S0040-4020(01)90393-X

Reference yield: 85.0%

chloromethyl p-tolylsulfone (7569-26-8) + sodium thiomethoxide (5188-07-8) → methylthiomethyl p-tolyl sulfone (59662-65-6)

Guidance literature:

In ethanol;

DOI:10.1016/S0040-4020(01)90393-X

upstream raw materials:

ethanol

1-benzenesulfonyl-1-methylsulfanyl-acetone

sodium 4-methylbenzenesulfinate

1-methylsulfanyl-1-(toluene-4-sulfonyl)-acetone

Downstream raw materials:

1-bromo-4-(methylsulfanylmethyl)benzene

1-bromo-2-[(methylthio)methyl]benzene

3-Methoxy-1-methylsulfanyl-1-(toluene-4-sulfonyl)-propan-2-one

1-Methylsulfanyl-1-(toluene-4-sulfonyl)-tridecan-2-one

Refernces

• 1、 Ogura, Katsuyuki,Uchida, Tohru,Tsuruda, Toshihiko,Takahashi, Kazumasa. "A NOVEL PREPARATION OF 3-METHYLTHIO-2-OXOPROPANAL ACETALS USING METHYLTHIOMETHYL p-TOLYL SULFONE". . p. 5703 - 5706. Retrieved 2007/10/02.
• 2、 Ogura, Katsuyuki,Yahata, Nobuhiro,Takahashi, Kazumasa,Iida, Hirotada. "A NOVEL ROUTE FROM A CARBOXYLIC ACID TO A CARBALDEHYDE USING METHYLTHIOMETHYL p-TOLYL SULFONE". . p. 5761 - 5762. Retrieved 2007/10/02.