1,3-Dibromoadamantane

Base Information

• Chemical Name: 1,3-Dibromoadamantane
• CAS No.: 876-53-9
• Molecular Formula: C10H14Br2
• Molecular Weight: 294.029
• Hs Code.: 2903890090
• Mol file: 876-53-9.mol

Synonyms:Adamantane,1,3-dibromo- (6CI,7CI,8CI);NSC 102289;

Chemical Property of 1,3-Dibromoadamantane

Chemical Property:

• Appearance/Colour: white solid
• Vapor Pressure: 0.00425mmHg at 25°C
• Melting Point: 108-110 °C
• Refractive Index: 1.651
• Boiling Point: 287.6 °C at 760 mmHg
• Flash Point: 145.4 °C
• PSA: 0.00000
• Density: 1.864 g/cm³
• LogP: 3.86760
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly)
• Water Solubility.: Soluble in organic solvents,insoluble in water.

Purity/Quality:

99% ^*data from raw suppliers

1,3-Dibromoadamantane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 1,3-Dibromoadamantane may be used in the preparation of 1,3-bis(phenyldimethylsilyl)adamantine.

Technology Process of 1,3-Dibromoadamantane

There total 25 articles about 1,3-Dibromoadamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

adamantane (281-23-2) → 1-Adamantyl bromide (768-90-1) + 1,3-dibromoadamantane (876-53-9)

Guidance literature:

With iron(III)-acetylacetonate; carbon tetrabromide; Reagent/catalyst; Sealed tube; Inert atmosphere;

DOI:10.1134/S1070428015020074

Reference yield: 97.3%

adamantane (281-23-2) → 1,3-dibromoadamantane (876-53-9)

Guidance literature:

With bromine; iron; In 1,1,2-Trichloro-1,2,2-trifluoroethane; at 30 ℃; for 8h;

Reference yield: 90.0%

3-bromoadamantane-1-carboxylic acid (21816-08-0) → 1,3-dibromoadamantane (876-53-9)

Guidance literature:

With [bis(acetoxy)iodo]benzene; potassium bromide; at 25 ℃; Irradiation;

DOI:10.1021/acs.oprd.0c00130

upstream raw materials:

N,N'-adamantane-1,3-diyl-bis-benzamide

adamantane

1-Adamantyl bromide

1-chloroadamantane

Downstream raw materials:

adamantane

adamantane-1,3-dicarboxylic acid

(1S,3R,6S,8R)-1,8-Dimethyl-4-aza-tricyclo[4.3.1.1^3,8]undecan-5-one

(+/-)-1,5-dimethylbicyclo<3.3.1>non-6-en-3-endo-carboxylic acid

Refernces

• 1、 Galukhin, Andrey,Islamov, Daut,Nikolaev, Ilya,Nosov, Roman,Taimova, Guzel,Vyazovkin, Sergey. "Polymerization kinetics of adamantane-based dicyanate ester and thermal properties of resulting polymer". . . Retrieved 2021/06/15.
• 2、 Kanazawa, Junichiro,Koyamada, Kenta,Miyamoto, Kazunori,Uchiyama, Masanobu,Watanabe, Ayumi. "Decarboxylative Bromination of Sterically Hindered Carboxylic Acids with Hypervalent Iodine(III) Reagents". supporting information. p. 1328 - 1334. Retrieved 2020/08/14.