2-Fluorophenanthrene

Base Information

• Chemical Name: 2-Fluorophenanthrene
• CAS No.: 523-41-1
• Molecular Formula: C14H9F
• Molecular Weight: 196.22
• Hs Code.: 2903999090
• DSSTox Substance ID: DTXSID90565815
• Nikkaji Number: J3.364.593G
• Wikidata: Q82451098
• Mol file: 523-41-1.mol

Synonyms:2-Fluorophenanthrene;523-41-1;SCHEMBL13818668;DTXSID90565815;AKOS006294924;A829038

Chemical Property of 2-Fluorophenanthrene

Chemical Property:

• Vapor Pressure: 0.000165mmHg at 25°C
• Refractive Index: 1.69
• Boiling Point: 340.9°C at 760 mmHg
• Flash Point: 129.7°C
• PSA: 0.00000
• Density: 1.212g/cm³
• LogP: 4.13210
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 196.068828449
• Heavy Atom Count: 15
• Complexity: 225

Purity/Quality:

98%min ^*data from raw suppliers

2-FLUOROPHENANTHRENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=C2C=CC(=C3)F

Technology Process of 2-Fluorophenanthrene

There total 19 articles about 2-Fluorophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-fluoro-2′-styryl-[1,1′-biphenyl]-2-carbaldehyde → 2-Fluor-phenanthren (523-41-1)

Guidance literature:

With phosphomolybdic acid; In 1,2-dichloro-ethane; at 25 ℃; for 12h; Sealed tube;

DOI:10.1021/acs.joc.1c02385

Reference yield: 99.0%

(4'-fluorobiphenyl-2-yl)acetaldehyde → 2-Fluor-phenanthren (523-41-1)

Guidance literature:

With trifluorormethanesulfonic acid; at 0 ℃; for 0.333333h;

DOI:10.1002/ejoc.201601406

Reference yield: 88.0%

C28H25FN4O4S2 (1392144-15-8) → 2-Fluor-phenanthren (523-41-1)

Guidance literature:

With dirhodium tetraacetate; lithium tert-butoxide; In toluene; at 90 ℃; for 1h; Inert atmosphere; Molecular sieve;

DOI:10.1002/anie.201201374

upstream raw materials:

(2-fluoro-fluoren-9-yl)-methanol

(E)-3-fluorostilbene

2-fluoro-9H-fluorene

C₂₈H₂₅FN₄O₄S₂

Refernces

• 1、 Akhmetov, Vladimir,Amsharov, Konstantin,Feofanov, Mikhail,Sharapa, Dmitry I.. "Alumina-Mediated π-Activation of Alkynes". supporting information. p. 15420 - 15426. Retrieved 2021/09/30.
• 2、 Chen, Ming,Zhao, Xinxin,Yang, Chao,Wang, Yanpei,Xia, Wujiong. "Further insight into the photochemical behavior of 3-aryl-N-(arylsulfonyl)propiolamides: tunable synthetic route to phenanthrenes". . p. 12022 - 12026. Retrieved 2017/03/01.