2-ISOPROPENYLNAPHTHALENE

Base Information

• Chemical Name: 2-ISOPROPENYLNAPHTHALENE
• CAS No.: 1855-47-6
• Molecular Formula: C13H12
• Molecular Weight: 168.238
• Hs Code.: 2902909090
• Mol file: 1855-47-6.mol

Synonyms:1-(1-methylethenyl)naphthalene;1-Isopropenylnaphthalene;1-isopropenyl-naphthalene;isopropenylnaphthalene;naphthalene,1-(1-methylethenyl);2-ISOPROPENYLNAPHTHALENE;2-ISOPROPENYLNAPHTHALENE 98+%

Chemical Property of 2-ISOPROPENYLNAPHTHALENE

Chemical Property:

• PSA: 0.00000
• LogP: 3.87290

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-ISOPROPENYL NAPHTHALENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-ISOPROPENYLNAPHTHALENE

There total 37 articles about 2-ISOPROPENYLNAPHTHALENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

isopropenylboronic acid (14559-87-6) + 1-Bromonaphthalene (90-11-9) → 1-(propen-2-yl)naphthalene (1855-47-6)

Guidance literature:

With cis,cis,cis-tetrakis[(diphenylphosphanyl)methyl]cyclopentane; potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)); In xylene; at 130 ℃; for 20h;

DOI:10.1002/ejoc.200300627

Reference yield: 94.0%

1-naphthalenecarbonyl fluoride (35424-74-9) + trimethylaluminum (75-24-1) → 1-(propen-2-yl)naphthalene (1855-47-6)

Guidance literature:

With bis-diphenylphosphinomethane; In toluene; at 120 ℃; for 24h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.9b01059

Reference yield: 91.6%

2-(naphthalen-1-yl)propan-2-ol (6301-54-8) → 1-(propen-2-yl)naphthalene (1855-47-6)

Guidance literature:

With sulfuric acid; for 1.33333h; Heating;

DOI:10.1248/cpb.42.1191

upstream raw materials:

2-(naphthalen-1-yl)propan-2-ol

oxalic acid

acetic anhydride

1-naphthylmagnesiumbromide

Downstream raw materials:

naphthalene

1-isopropylnaphthalene

Refernces

• 1、 Barasz, Jonah A.,Ghaffari, Ali H.,Otte, Douglas A.,Thamattoor, Dasan M.. "An unusual, DDQ-promoted oxidative rearrangement of 9,9-disubstituted 1,4,5,8-tetrahydro-4a,8a-methanonaphthalenes". . p. 64 - 65. Retrieved 2002.
• 2、 Zhao, Bin,Pan, Zichen,Zhu, Anqiao,Yue, Yanni,Ma, Mengtao,Xue, Fei. "Electrochemical fluorosulfonylation of alkenes to access vicinal fluorinated sulfones derivatives". supporting information. . Retrieved 2022/01/24.
• 3、 Liu, Zhili,Chen, Lianfen,Zhu, Dong,Zhu, Shifa. "Formal Allylation and Enantioselective Cyclopropanation of Donor/Acceptor Rhodium(II) Azavinyl Carbenes". supporting information. p. 1275 - 1279. Retrieved 2021/02/20.