2,2,3,3-Tetrafluoropropyl acetate

Base Information

• Chemical Name: 2,2,3,3-Tetrafluoropropyl acetate
• CAS No.: 681-58-3
• Molecular Formula: C5H6F4O2
• Molecular Weight: 174.09
• Hs Code.: 2915390090
• DSSTox Substance ID: DTXSID30520988
• Nikkaji Number: J2.757.680J
• Wikidata: Q82385192
• Mol file: 681-58-3.mol

Synonyms:2,2,3,3-TETRAFLUOROPROPYL ACETATE;681-58-3;MFCD16620590;2,2,3,3-TETRAFLUOROPROPYL ACETATE> 95 %;SCHEMBL2536484;DTXSID30520988;AKOS006373856;2,2,3,3-TETRAFLUOROPROPYLACETATE;1-Propanol, 2,2,3,3-tetrafluoro-, acetate

Chemical Property of 2,2,3,3-Tetrafluoropropyl acetate

Chemical Property:

• Vapor Pressure: 42.792mmHg at 25°C
• Refractive Index: 1.326
• Boiling Point: 96.842°C at 760 mmHg
• Flash Point: 13.186°C
• PSA: 26.30000
• Density: 1.273g/cm³
• LogP: 1.44990
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 174.03039208
• Heavy Atom Count: 11
• Complexity: 145

Purity/Quality:

99% ^*data from raw suppliers

2,2,3,3-Tetrafluoropropyl acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OCC(C(F)F)(F)F

Technology Process of 2,2,3,3-Tetrafluoropropyl acetate

There total 9 articles about 2,2,3,3-Tetrafluoropropyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

acetic anhydride (108-24-7) + C12H12F16O4Te (85878-21-3) → 2,2,3,3-tetrafluoropropyl acetate (681-58-3) + tris(2,2,3,3-tetrafluoropropyloxy)acetoxytellurane (107937-89-3)

Guidance literature:

at 20 ℃; for 2h; Yields of byproduct given; ether as solvent;;

Reference yield: 80.0%

acetic anhydride (108-24-7) + C12H12F16O4Te (85878-21-3) → 2,2,3,3-tetrafluoropropyl acetate (681-58-3)

Guidance literature:

at 80 - 120 ℃;

Reference yield:

2,2,3,3-tetrafluror-1-propanol + toluol-4-sulfonic acid monohydrate + diethyl ether (60-29-7,927820-24-4) + acetic anhydride (108-24-7) → 2,2,3,3-tetrafluoropropyl acetate (681-58-3)

Guidance literature:

In water;

upstream raw materials:

tris(2,2,3,3-tetrafluoropropyl)phosphite

acetic acid

Acetyl bromide

phosphonic acid bis-(2,2,3,3-tetrafluoro-propyl) ester

Refernces

• 1、 -. "Method for fabricating a high specific surface area mesoporous alumina". . . Retrieved 2008/06/13.
• 2、 Aleinikov, S. F.,Krutikov, V. I.,Golovanov, A. V.,Lavrent'ev, A. N.. "REACTION OF BIS(2,2,3,3-TETRAFLUOROPROPYL) HYDROGEN PHOSPHITE WITH ACETYL BROMIDE". . p. 1709. Retrieved 2007/10/02.