tert-Amyl oxalate

Base Information

• Chemical Name: tert-Amyl oxalate
• CAS No.: 690-71-1
• Molecular Formula: C7H11O4-
• Molecular Weight: 230.304
• Hs Code.: 2917119000
• Mol file: 690-71-1.mol

Synonyms:tert-Amyl oxalate

Chemical Property of tert-Amyl oxalate

Chemical Property:

• PSA: 66.43000
• LogP: -0.53190

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tert-Amyl oxalate

There total 1 articles about tert-Amyl oxalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-Amyl alcohol (75-85-4) + oxalyl dichloride (79-37-8) → di-tert-pentyl oxalate (690-71-1)

Guidance literature:

With pyridine; In diethyl ether;

DOI:10.1021/jo01014a007

Reference yield: 73.0%

O-benzyl carbamate (621-84-1) + di-tert-pentyl oxalate (690-71-1) → benzyl tert-pentyl carbamate

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In 1,2-dichloro-ethane; at 40 ℃; for 12h; Sealed tube; Schlenk technique;

DOI:10.1021/acs.orglett.0c04206

Reference yield:

di-tert-pentyl oxalate (690-71-1) → 2-methyl-but-2-ene (513-35-9)

Guidance literature:

at 140 ℃;

DOI:10.1021/jo01014a007

upstream raw materials:

tert-Amyl alcohol

oxalyl dichloride

Downstream raw materials:

2-methyl-but-2-ene