1,1-BIS(MORPHOLINO)ETHYLENE

Base Information

• Chemical Name: 1,1-BIS(MORPHOLINO)ETHYLENE
• CAS No.: 14212-87-4
• Molecular Formula: C10H18 N2 O2
• Molecular Weight: 198.265
• Hs Code.: 2934999090
• Mol file: 14212-87-4.mol

Synonyms:Morpholine,4,4'-vinylidenedi- (7CI,8CI); 1,1-Dimorpholinoethene; 1,1-Dimorpholinoethylene

Chemical Property of 1,1-BIS(MORPHOLINO)ETHYLENE

Chemical Property:

• Boiling Point: 350.2oC at 760 mmHg
• Flash Point: 110.7oC
• PSA: 24.94000
• Density: 1.109g/cm3
• LogP: -0.00220

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1-bis(Morpholino)ethylene ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1-BIS(MORPHOLINO)ETHYLENE

There total 3 articles about 1,1-BIS(MORPHOLINO)ETHYLENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

morpholine (110-91-8,99108-56-2) + N,N-dimethylacetamide dimethyl acetal (18871-66-4) → 1,1-bis(N-morpholinyl)ethylene (14212-87-4)

Guidance literature:

at 190 ℃; for 5h;

DOI:10.1055/s-2002-20453

Reference yield:

3-benzyl-1,3-oxazolidine (13657-16-4) + (E)-1-(N-morpholino)propene (51043-49-3) → 1,1-bis(N-morpholinyl)ethylene (14212-87-4) + 2-Methyl-3-morpholinopropionaldehyde + 4-Benzyl-6-methyl-7-morpholinohexahydro-1,4-oxazepin (343233-65-8)

Guidance literature:

With trifluoroacetic acid; Yield given. Multistep reaction. Yields of byproduct given; 1) THF, 30 min, room temperature, 2) 3 h, room temperature;

Reference yield:

→ 1,1-bis(N-morpholinyl)ethylene (14212-87-4)

Guidance literature:

Keten-diethylacetal, Morpholin, 100grad;

upstream raw materials:

3-benzyl-1,3-oxazolidine

(E)-1-(N-morpholino)propene

morpholine

N,N-dimethylacetamide dimethyl acetal

Downstream raw materials:

1-[1-(4-methoxy-phenyl)-5,5-di-morpholin-4-yl-4,5-dihydro-1H-pyrazol-3-yl]-ethanone

3,3-Di-morpholin-4-yl-1-phenyl-propenone

N-(4-chloro-phenyl)-3,3-di-morpholin-4-yl-acrylamide

3-(1-benzoyl-3,3-di-morpholin-4-yl-allyl)-1-benzyl-1,3-dihydro-indol-2-one

Refernces

• 1、 -. "Catalyst compositions for trimerizing organic isocyanates". . . Retrieved 2008/06/13.