ALLYL PHENYL SELENIDE

Base Information

• Chemical Name: ALLYL PHENYL SELENIDE
• CAS No.: 14370-82-2
• Molecular Formula: C9H10 Se
• Molecular Weight: 197.138
• Hs Code.: 2931900090
• Mol file: 14370-82-2.mol

Synonyms:Benzene,(2-propenylseleno)- (9CI); Selenide, allyl phenyl (8CI); (Allylseleno)benzene;Allyl phenyl selenide; Phenyl allyl selenide

Chemical Property of ALLYL PHENYL SELENIDE

Chemical Property:

• Melting Point: 10℃
• Refractive Index: n20/D 1.598
• Boiling Point: 109-110℃ (37 Torr)
• PSA: 0.00000
• Density: 1.308 g/mL at 20 °C(lit.)
• LogP: 1.62040
• Storage Temp.: 2-8°C

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 23/25-33-50/53
• Safety Statements: 20/21-28-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ALLYL PHENYL SELENIDE

There total 49 articles about ALLYL PHENYL SELENIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenyl diselenide (1666-13-3) + allyl bromide (106-95-6) → allyl phenyl selenide (14370-82-2)

Guidance literature:

With sodium dihydrogenphosphate; zinc; In water; acetonitrile; for 1h;

DOI:10.1016/S0040-4039(01)00820-6

Reference yield: 98.0%

allyl iodid (556-56-9) + diphenyl diselenide (1666-13-3) → allyl phenyl selenide (14370-82-2)

Guidance literature:

diphenyl diselenide; With 1-butyl-3-methylimidazolium Tetrafluoroborate; zinc; at 20 ℃; Inert atmosphere;

allyl iodid; at 20 ℃; Inert atmosphere;

DOI:10.1021/jo100454m

Reference yield: 96.0%

ethyl 2-(phenylselanyl)acetate (51364-94-4) + allyl bromide (106-95-6) → allyl phenyl selenide (14370-82-2) + ethyl 2-(phenylselanyl)pent-4-enoate (308335-59-3)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; In tetrahydrofuran; at -78 - 0 ℃; for 0.5h;

DOI:10.1016/S0040-4020(00)00647-5

upstream raw materials:

allyl iodid

Thallous Phenyl Selenide

Allyl acetate

diphenyl diselenide

Downstream raw materials:

Trimethyl-(1-phenylselanyl-allyl)-silane

(E)-1-(4-Nitro-phenyl)-hex-3-en-1-ol

2-Ethyl-1-(4-nitro-phenyl)-but-3-en-1-ol

(3Z)-1-phenyl-3-hexen-1-ol

Refernces

• 1、 Yu, Mingxin,Zhang, Yongmin,Bao, Weiliang. "The synthesis of allyl selenides by organosamarium reagent". . p. 609 - 613. Retrieved 1997.
• 2、 Weber, J. V.,Faller, P.,Kirsch, G.,Schneider, M.. "Simple Synthesis of Organyl Phenyl Selenides from Exchange Resin-Supported Phenyl Selenide Anion". . p. 1044 - 1045. Retrieved 1984.
• 3、 Narayanaperumal, Senthil,Alberto, Eduardo E.,Gul, Kashif,Rodrigues, Oscar E. D.,Braga, Antonio L.. "Synthesis of diorganyl selenides mediated by zinc in ionic liquid". . p. 3886 - 3889. Retrieved 2010.
• 4、 Wallner, Olov A.,Szabo, Kalman J.. "Employment of palladium pincer-complexes in phenylselenylation of organohalides". . p. 9215 - 9221. Retrieved 2005.
• 5、 Zheng,Bao,Zhang. "A novel synthesis of allyl and propargyl selenides promoted by indium". . p. 79 - 83. Retrieved 1997.
• 6、 Zhao, Xiaodan,Yu, Zhengkun,Yan, Shenggang,Wu, Sizhong,Liu, Ren,He, Wei,Wang, Liandi. "Ruthenium(III) chloride catalyzed efficient synthesis of unsymmetrical diorganyl selenides via cleavage of dibenzyl and diphenyl diselenides in the presence of zinc". . p. 7338 - 7341. Retrieved 2005.
• 7、 Wang, Lingxiao,Qiao, Jie,Wei, Jiancong,Liang, Zhiwu,Xu, Xinhua,Li, Ningbo. "Air-stable binuclear Titanium(IV) salophen perfluorobutanesulfonate with zinc power catalytic system and its application to C–S and C–Se bond formation". . . Retrieved 2020/01/08.
• 8、 Jana, Sripati,Koenigs, Rene M.. "Rhodium-Catalyzed Carbene Transfer Reactions for Sigmatropic Rearrangement Reactions of Selenium Ylides". supporting information. p. 3653 - 3657. Retrieved 2019/05/24.