DIMETHYL ETHYLPHOSPHONATE

Base Information

• Chemical Name: DIMETHYL ETHYLPHOSPHONATE
• CAS No.: 6163-75-3
• Molecular Formula: C4H11O3P
• Molecular Weight: 138.103
• Hs Code.: 2931900090
• Mol file: 6163-75-3.mol

Synonyms:DIMETHYL ETHYLPHOSPHONATE;Ethylphosphonic acid, dimethyl ester;Ethylphosphonic acid, Me;ethyl-phosphonicaciddimethylester;Phosphonic acid, ethyl-, dimethyl ester

Chemical Property of DIMETHYL ETHYLPHOSPHONATE

Chemical Property:

• Refractive Index: 1.4128
• Boiling Point: 61-62℃/6mm
• PSA: 45.34000
• Density: 1.103
• LogP: 1.49220
• Sensitive.: Air & Moisture Sensitive

Purity/Quality:

99% ^*data from raw suppliers

DIMETHYL ETHYLPHOSPHONATE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of DIMETHYL ETHYLPHOSPHONATE

There total 4 articles about DIMETHYL ETHYLPHOSPHONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylphosphonic acid diethyl ester (78-38-6) + methyl p-toluene sulfonate (80-48-8) → dimethyl ethylphosphonate (6163-75-3) + Ethyl methyl ethylphosphonate (5301-65-5) + ethyl ester of p-toluenesulfonic acid (80-40-0)

Guidance literature:

at 130 - 140 ℃; for 3.5h;

DOI:10.1021/jo01255a043

Reference yield:

azoethane (821-14-7) + benzyl dimethyl phosphite (56153-57-2) → dimethyl ethylphosphonate (6163-75-3) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7)

Guidance literature:

With phosphoric acid tripropyl ester; In benzene-d6; at 24 ℃; for 14h; Irradiation;

DOI:10.1021/ja962287z

Reference yield:

ethyl iodide (75-03-6) + phosphorous acid trimethyl ester (121-45-9) → dimethyl ethylphosphonate (6163-75-3) + dimethyl methane phosphonate (756-79-6)

Guidance literature:

for 0.0833333h; microwave irradiation;

DOI:10.1080/10426500008043680

upstream raw materials:

ethylphosphonic acid diethyl ester

methyl p-toluene sulfonate

azoethane

benzyl dimethyl phosphite

Downstream raw materials:

(Z)-diphenyl 1-methyl 1,2-propenylphosphine oxide

(E)-diphenyl 1-methyl 1,2-propenylphosphine oxide

trichlorophosphate

methyl phenyl ethylphosphonate

Refernces

• 1、 Dockery, Kevin P.,Bentrude, Wesley G.. "Free radical chain reactions of [1.1.1]propellane with three-coordinate phosphorus molecules. Evidence for the high reactivity of the bicyclo[1.1.1]pent-1-yl radical". . p. 1388 - 1399. Retrieved 2007/10/03.