N-methylnonadecanamide

Base Information

• Chemical Name: N-methylnonadecanamide
• CAS No.: 6212-93-7
• Molecular Formula: C10H21NO
• Molecular Weight: 171.283
• Hs Code.: 2924199090
• DSSTox Substance ID: DTXSID00369240
• Nikkaji Number: J1.857.400D
• Wikidata: Q82156286
• Mol file: 6212-93-7.mol

Synonyms:N-methylnonadecanamide;6212-93-7;NONADECANOIC ACID N-METHYLAMIDE;SCHEMBL1721713;DTXSID00369240;FT-0707327

Chemical Property of N-methylnonadecanamide

Chemical Property:

• Melting Point: 91-94 °C
• Refractive Index: 1.5614 (estimate)
• Boiling Point: 451.57°C (rough estimate)
• PSA: 32.59000
• Density: 0.9304 (rough estimate)
• LogP: 7.22430
• XLogP3: 7.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 17
• Exact Mass: 311.318814931
• Heavy Atom Count: 22
• Complexity: 228

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCCCCCCC(=O)NC

Technology Process of N-methylnonadecanamide

There total 1 articles about N-methylnonadecanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-Butyl-N-nitrosopelargonamide (91083-85-1) + methylamine (74-89-5) → N-Methylpelargonamide (6212-93-7) + n-butyl nonanoate (50623-57-9)

Guidance literature:

In dichloromethane; for 4h; Yield given; Heating;

DOI:10.1016/S0040-4039(00)87040-9

Reference yield:

N-Methylpelargonamide (6212-93-7) → nonanamide (1120-07-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 100 percent / NO₂, NaOAc / CH₂Cl₂ / -20 °C

2: 85 percent / 7M NH₃-MeOH / CH₂Cl₂ / 48 h / Ambient temperature

With methanol; ammonium hydroxide; sodium acetate; Nitrogen dioxide; In dichloromethane;

DOI:10.1021/jo00192a014

Reference yield:

N-Methylpelargonamide (6212-93-7) → nonanoic acid methyl ester (1731-84-6)

Guidance literature:

Multi-step reaction with 2 steps

1: N₂O₄, AcONa / CH₂Cl₂ / -15 °C

2: CH₂Cl₂ / Heating; week-end

With sodium acetate; dinitrogen tetraoxide; In dichloromethane;

DOI:10.1016/S0040-4039(00)87040-9

upstream raw materials:

N-Butyl-N-nitrosopelargonamide

methylamine

Downstream raw materials:

n-nonyl-n-methylamine

1-(pyrrolidin-1-yl)nonan-1-one

nonanamide

octanecarboxylic acid dimethylamide

Refernces