4-AMINOPHENYL-BETA-L-FUCOPYRANOSIDE

Base Information

• Chemical Name: 4-AMINOPHENYL-BETA-L-FUCOPYRANOSIDE
• CAS No.: 69936-58-9
• Molecular Formula: C12H17NO5
• Molecular Weight: 255.271
• Hs Code.: 29389090
• Mol file: 69936-58-9.mol

Synonyms:4-AMINOPHENYL-BETA-L-FUCOPYRANOSIDE;P-AMINOPHENYL-BETA-L-FUCOPYRANOSIDE;P-aminophenyl-B-L-fucopyranoside;4-Aminophenylb-L-fucopyranoside

Chemical Property of 4-AMINOPHENYL-BETA-L-FUCOPYRANOSIDE

Chemical Property:

• Melting Point: 175℃
• Boiling Point: 489℃
• Flash Point: 249℃
• PSA: 105.17000
• Density: 1.416
• LogP: 0.05630
• Storage Temp.: ?20°C

Purity/Quality:

98% ^*data from raw suppliers

4-Aminophenyl b-L-fucopyranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-AMINOPHENYL-BETA-L-FUCOPYRANOSIDE

There total 1 articles about 4-AMINOPHENYL-BETA-L-FUCOPYRANOSIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-(4-nitrophenyl)-β-L-fucopyranoside (22153-71-5) → p-aminophenyl-β-L-fucopyranoside (69936-58-9)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In methanol; for 7h; under 2068.65 Torr;

DOI:10.1021/acs.joc.0c01812

Reference yield: 90.0%

3,5-dihydroxyphenol (108-73-6) + p-aminophenyl-β-L-fucopyranoside (69936-58-9) → C42H48N6O18

Guidance literature:

p-aminophenyl-β-L-fucopyranoside; With hydrogenchloride; sodium nitrite; In water; at 0 ℃; for 3h;

3,5-dihydroxyphenol; With sodium hydroxide; pH=Ca. 11;

DOI:10.1021/acs.joc.0c01812

Reference yield: 80.9%

6-(tert-butoxycarbonylamino)hexanoic acid (6404-29-1) + p-aminophenyl-β-L-fucopyranoside (69936-58-9) → p-(N-Boc-6-aminohexanoyl)amino-phenyl-β-L-fucopyranoside (69936-59-0)

Guidance literature:

With dicyclohexyl-carbodiimide; In pyridine; 1.) 4 deg C, 4 h, 2.) 20 deg C, 5 days;

upstream raw materials:

1-(4-nitrophenyl)-β-L-fucopyranoside

Downstream raw materials:

p-(N-Boc-6-aminohexanoyl)amino-phenyl-β-L-fucopyranoside

Refernces

• 1、 Klyashchitskii, B. A.,Pozdnev, V. F.,Beier, E. M.. "COVALENT ADDITION OF BIOLOGICALLY ACTIVE SUBSTANCES TO POLYMERS IV. SYNTHESIS OF AFFINITY ADSORBENTS CONTAINING L-FUCOSE DERIVATIVES". . p. 178 - 182. Retrieved 2007/10/02.