3-Phenoxypropyltrichlorosilane

Base Information

• Chemical Name: 3-Phenoxypropyltrichlorosilane
• CAS No.: 60333-76-8
• Molecular Formula: C9H11Cl3OSi
• Molecular Weight: 269.63
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID20529309
• Nikkaji Number: J1.903.085G
• Wikidata: Q82399662
• Mol file: 60333-76-8.mol

Synonyms:3-PHENOXYPROPYLTRICHLOROSILANE;60333-76-8;trichloro(3-phenoxypropyl)silane;SCHEMBL524338;DTXSID20529309;MFCD01320968

Chemical Property of 3-Phenoxypropyltrichlorosilane

Chemical Property:

• Vapor Pressure: 0.002mmHg at 25°C
• Refractive Index: 1.519
• Boiling Point: 301.628 °C at 760 mmHg
• Flash Point: 113.75 °C
• PSA: 9.23000
• Density: 1.246 g/cm³
• LogP: 4.11080
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 267.964475
• Heavy Atom Count: 14
• Complexity: 155

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OCCC[Si](Cl)(Cl)Cl

Technology Process of 3-Phenoxypropyltrichlorosilane

There total 4 articles about 3-Phenoxypropyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.3%

allyl phenyl ether (1746-13-0) → 3-phenoxypropyltrichlorosilane (60333-76-8)

Guidance literature:

With bis(dimethylamino)chlorocarbenium hexachloroplatinate; trichlorosilane; at 70 ℃; for 3h;

DOI:10.1007/BF02496134

Reference yield:

oct-1-ene (111-66-0,25068-25-1) → 3-phenoxypropyltrichlorosilane (60333-76-8)

Guidance literature:

With triethyl borane; trichlorosilane; In tetrahydrofuran; at 0 - 20 ℃; In air;

DOI:10.1055/s-0031-1289568

Reference yield:

allyl phenyl ether (1746-13-0) → phenoxytrichlorosilane (3410-96-6) + 3-phenoxypropyltrichlorosilane (60333-76-8) + dichloro-(3-phenoxy-propyl)-silane

Guidance literature:

With cyanex-921; trichlorosilane; nickel dichloride; at 125 ℃; for 25h; Inert atmosphere;

DOI:10.1134/S1070363210040079

upstream raw materials:

allyl phenyl ether

oct-1-ene

Downstream raw materials:

3-phenoxypropanol

C₂₄H₃₈O₇Si

triethylamine hydrochloride

1-(3-Phenoxy-propyl)-2,8,9-trioxa-1-sila-tricyclo[3.3.1.1^3,7]decane

Refernces

• 1、 Belyakova,Pomerantseva,Efimova,Chernyshev,Storozhenko. "Effect of catalysts on the reaction of allyl esters with hydrosilanes". experimental part. p. 728 - 733. Retrieved 2011/01/05.