1,1'-Binaphthalene, 2,2'-dimethyl-

Base Information Edit

Chemical Name:1,1'-Binaphthalene, 2,2'-dimethyl-
CAS No.:60536-98-3
Molecular Formula:C₂₂H₁₈
Molecular Weight:282.385
Hs Code.:
European Community (EC) Number:620-906-5
DSSTox Substance ID:DTXSID30186503
Nikkaji Number:J145.017D,J3.236.709G,J3.594.958E
Mol file:60536-98-3.mol

Synonyms:2,2'-Dimethyl-1,1'-binaphthalene;1,1'-Binaphthalene, 2,2'-dimethyl-;19634-89-0;60536-98-3;(R)-2,2'-Dimethyl-1,1'-binaphthyl;32834-84-7;(R)-2,2'-Dimethyl-1,1'-binaphthalene;2-methyl-1-(2-methylnaphthalen-1-yl)naphthalene;2,2'-Dimethyl-1,1'-binaphthyl;1,1'-Binaphthyl, 2,2'-dimethyl-;2 2'-DIMETHYL-1 1'-BINAPHTHYL 90;MFCD01863647;52889-79-9;DTXSID30186503;AKOS004908869;2,2'-Dimethyl-1,1'-binaphthalene, 90%;CS-0085877;D2837;D2838;FT-0729632;D95420;W-201727

Suppliers and Price of 1,1'-Binaphthalene, 2,2'-dimethyl-

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,2''-Dimethyl-1,1''-binaphthalene
2.5g
$ 275.00

Sigma-Aldrich
2,2′-Dimethyl-1,1′-binaphthalene 90%
1g
$ 158.00

Sigma-Aldrich
2,2′-Dimethyl-1,1′-binaphthalene 90%
10g
$ 856.00

American Custom Chemicals Corporation
2,2'-DIMETHYL-1,1'-BINAPHTHALENE 90.00%
10G
$ 1867.64

American Custom Chemicals Corporation
2,2'-DIMETHYL-1,1'-BINAPHTHALENE 90.00%
1G
$ 762.22

Total 3 raw suppliers

Chemical Property of 1,1'-Binaphthalene, 2,2'-dimethyl- Edit

Chemical Property:

Boiling Point:190-210 °C0.2 mm Hg(lit.)
Flash Point:>230 °F
PSA：0.00000
LogP:6.27680
XLogP3:6.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:282.140850574
Heavy Atom Count:22
Complexity:336

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,2''-Dimethyl-1,1''-binaphthalene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)C
Uses 2,2''-Dimethyl-1,1''-binaphthalene (cas# 60536-98-3) is a compound useful in organic synthesis.

Technology Process of 1,1'-Binaphthalene, 2,2'-dimethyl-

There total 48 articles about 1,1'-Binaphthalene, 2,2'-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 2586-62-1
1-bromo-2-methylnaphtalene

: 103989-84-0
2-methyl-1-naphthylboronic acid

: 60536-98-3,19634-89-0,32587-64-7,32834-84-7
2,2'-dimethyl-1,1'-binaphthyl

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; caesium carbonate; In tetrahydrofuran; for 30h; Inert atmosphere; Reflux;
DOI:10.1016/j.jorganchem.2011.04.031

Reference yield: 100.0%

: 75-16-1
methylmagnesium bromide

: 141807-44-5,126613-06-7,128544-05-8,128575-34-8
(+/-)-2,2'-bis(trifluoromethanesulfonyloxy)-1,1-binaphthyl

: 60536-98-3,19634-89-0,32587-64-7,32834-84-7
2,2'-dimethyl-1,1'-binaphthyl

Guidance literature:: With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In diethyl ether; at 0 ℃; for 24h; Reflux;
DOI:10.1002/anie.201201374

Reference yield: 98.0%

: 2586-62-1
1-bromo-2-methylnaphtalene

: 21450-90-8
(2-methyl-1-naphthyl)magnesium bromide

: 60536-98-3,19634-89-0,32587-64-7,32834-84-7
2,2'-dimethyl-1,1'-binaphthyl

Guidance literature:: With [Pd(μ-Cl)Cl(N,N′-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene)]₂; In 1,4-dioxane; at 60 ℃; for 16h; Inert atmosphere; Glovebox;
DOI:10.1039/c4ob01269k