cis-2-Dodecene

Base Information

• Chemical Name: cis-2-Dodecene
• CAS No.: 7206-26-0
• Molecular Formula: C12H24
• Molecular Weight: 168.323
• DSSTox Substance ID: DTXSID201018096
• Nikkaji Number: J97.388B
• Wikidata: Q106040198
• Mol file: 7206-26-0.mol

Synonyms:cis-2-dodecene;(2Z)-2-Dodecene;2-Dodecene, (Z)-;(Z)-2-Dodecene;(Z)-dodec-2-ene;(2Z)-DODEC-2-ENE;7206-26-0;cis-dodec-2-ene;ADOQBZAVKYCFOI-HYXAFXHYSA-N;CHEBI:167556;DTXSID201018096

Chemical Property of cis-2-Dodecene

Chemical Property:

• Vapor Pressure: 0.208mmHg at 25°C
• Melting Point: -38.4°C (estimate)
• Refractive Index: 1.437
• Boiling Point: 216.2°C at 760 mmHg
• Flash Point: 74.8°C
• PSA: 0.00000
• Density: 0.764g/cm³
• LogP: 4.70320
• XLogP3: 6.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 168.187800766
• Heavy Atom Count: 12
• Complexity: 92.2

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCC=CC
• Isomeric SMILES: CCCCCCCCC/C=C\C

Technology Process of cis-2-Dodecene

There total 4 articles about cis-2-Dodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-dodecene (112-41-4,25067-08-7,62132-67-6) → dodecane (112-40-3) + (Z)-dodec-2-ene (7206-26-0) + (E)-2-dodecene (7206-13-5)

Guidance literature:

With hydrogen; Pd₆Ru₆; at 99.85 ℃; for 4h; under 15001.2 Torr; Further Variations:; Catalysts; Product distribution;

DOI:10.1039/a901263j

Reference yield:

2-(tosyloxy)dodecane (102736-19-6) → dodecane (112-40-3) + 1-dodecene (112-41-4,25067-08-7,62132-67-6) + (Z)-dodec-2-ene (7206-26-0) + (E)-2-dodecene (7206-13-5)

Guidance literature:

With sodium tetrahydroborate; (1R,2R)-(-)-N,N'-bis(3,5-di-tert-butylsalicydene)-1,2-cyclohexanediaminocobalt(II); vitamin B₁₂; sodium hydrogencarbonate; In acetonitrile; at 20 ℃; for 18h; Overall yield = 100 percentSpectr.; Inert atmosphere; Irradiation;

DOI:10.1039/d0sc05925k

Reference yield:

N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate (73377-34-1) → 5,6,8,9-tetrahydro-7-phenyldibenzolacridine (57366-68-4) + 1-dodecene (112-41-4,25067-08-7,62132-67-6) + (Z)-dodec-2-ene (7206-26-0) + (E)-2-dodecene (7206-13-5)

Guidance literature:

With triphenylpyridine; at 150 ℃; Yield given. Yields of byproduct given;

DOI:10.1039/c39810000096

upstream raw materials:

N-n-dodecyl-5,6,8,9-tetrahydro-7-phenyldibenzacridinium trifluoromethanesulfonate

1-dodecene

dodecane

2-(tosyloxy)dodecane

Refernces

• 1、 Raja, Robert,Sankar, Gopinathan,Hermans, Sophie,Shephard, Douglas S.,Bromley, Stefan,Thomas, John Meurig,Johnson, Brian F.G.. "Preparation and characterisation of a highly active bimetallic (Pd-Ru) nanoparticle heterogeneous catalyst". . p. 1571 - 1572. Retrieved 2007/10/03.
• 2、 Katritzky, Alan R.,El-Mowafy, Azzahra M.. "The Conversion of Primary Amines into Olefins: a Mild Alternative to the Hofmann Elimination". . p. 96. Retrieved 2007/10/02.