IODOBENZENE-D5

Base Information

• Chemical Name: IODOBENZENE-D5
• CAS No.: 7379-67-1
• Molecular Formula: C6D5I
• Molecular Weight: 208.971
• Mol file: 7379-67-1.mol

Synonyms:IODOBENZENE-D5;IODOBENZENE-D5, 98+ ATOM % D

Chemical Property of IODOBENZENE-D5

Chemical Property:

• Melting Point: -29 °C(lit.)
• Refractive Index: n20/D 1.6161(lit.)
• Boiling Point: 188 °C(lit.)
• Flash Point: 74 °C
• PSA: 0.00000
• Density: 1.868 g/mL at 25 °C
• LogP: 2.29120

Purity/Quality:

98.5% ^*data from raw suppliers

Iodobenzene-d5 ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36-41-20
• Safety Statements: 26-36-39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of IODOBENZENE-D5

There total 3 articles about IODOBENZENE-D5 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

benzene-d6 (1076-43-3) → d5-iodobenzene (7379-67-1)

Guidance literature:

With iodine; silver trifluoromethanesulfonate; In dichloromethane; for 0.5h; Darkness;

DOI:10.1002/anie.201710049

Reference yield:

iodobenzene (591-50-4) → d5-iodobenzene (7379-67-1)

Guidance literature:

With trifluoroacetic acid-d₁; [Rh(bdmpza)Cl₃](-)Na(+); silver trifluoromethanesulfonate; at 100 ℃; for 24h; Inert atmosphere;

DOI:10.1021/om2012419

Reference yield:

→ d5-iodobenzene (7379-67-1)

Guidance literature:

Benzol-d(6), Iod, Iodsaeure, Essigsaeure-d(4), Schwefelsaeure-d(2), D2O;

DOI:10.1002/jlcr.2590060212

upstream raw materials:

benzene-d6

iodobenzene

Downstream raw materials:

1-[2-(d5-phenylethynyl)phenyl]-3-trimethylsilyl-2-propyn-1-ol

triphenylphosphine-d15

5-(methyl-d3)-1-(phenyl-d5)-pyridin-2(1H)-one

Refernces

• 1、 Ge, Qingmei,Li, Bin,Wang, Baiquan. "Synthesis of substituted benzo[ij]imidazo[2,1,5-de]quinolizine by rhodium(iii)-catalyzed multiple C-H activation and annulations". . p. 1814 - 1821. Retrieved 2016.
• 2、 Wang, Qi,Zang, Zhong-Lin,Jie, Mi,Luo, Li-Hua,Yang, Dan,Zhou, Cheng-He,Cai, Gui-Xin. "Ligand-Controlled, Tunable Copper-Catalyzed Radical Divergent Trifluoromethylation of Unactivated Cycloalkenes". supporting information. p. 5284 - 5291. Retrieved 2021/10/25.
• 3、 Kaishap, Partha P.,Duarah, Gauri,Sarma, Bipul,Chetia, Dipak,Gogoi, Sanjib. "Ruthenium(II)-Catalyzed Synthesis of Spirobenzofuranones by a Decarbonylative Annulation Reaction". supporting information. p. 456 - 460. Retrieved 2018/02/21.