sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle

Base Information

• Chemical Name: sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle
• CAS No.: 107647-26-7
• Molecular Formula: C₁₃H₁₅NS
• Molecular Weight: 217.335
• Mol file: 107647-26-7.mol

Synonyms:

Chemical Property of sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle

There total 1 articles about sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

bis[2-(N,N-dimethylamino)phenyl] disulfide (18206-22-9) + (3-methyl-but-3-en-1-ynyl)-lithium (38341-85-4) → sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle (107647-26-7)

Guidance literature:

In tetrahydrofuran; diethyl ether; for 16h; Ambient temperature;

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle (107647-26-7) → methyl-4 phenyl-1 penten-4 yn-2 ol-1 (137935-62-7,1595-49-9) + sulfure de n.butyle et d'o.dimethylamino-phenyle (74642-18-5)

Guidance literature:

With benzaldehyde; Yield given. Multistep reaction. Yields of byproduct given; 1.) ether/hexane, 0 deg C, 5 h, 2.) 0 deg C, 2 h;

Reference yield:

tert.-butyl lithium (594-19-4) + sulfure de (dimethylamino-2) phenyle et de (methyl-3 buten-3 yn-1) yle (107647-26-7) → methyl-4 phenyl-1 penten-4 yn-2 ol-1 (137935-62-7,1595-49-9) + sulfure de (dimethyl-1',1')ethyle et d'o.dimethylamino-phenyle

Guidance literature:

With benzaldehyde; Yield given. Multistep reaction. Yields of byproduct given; 1.) ether/hexane, 0 deg C, 5 h, 2.) 0 deg C, 2 h;

upstream raw materials:

bis[2-(N,N-dimethylamino)phenyl] disulfide

(3-methyl-but-3-en-1-ynyl)-lithium

Downstream raw materials:

methyl-4 phenyl-1 penten-4 yn-2 ol-1

sulfure de n.butyle et d'o.dimethylamino-phenyle

Refernces