[Zr(η5-C5H5)(η5-C9H7)(C6H5)2]

Base Information

• Chemical Name: [Zr(η5-C5H5)(η5-C9H7)(C6H5)2]
• CAS No.: 301336-68-5
• Molecular Formula: C₂₆H₂₂Zr
• Molecular Weight: 425.685
• Mol file: 301336-68-5.mol

Synonyms:

Chemical Property of [Zr(η5-C5H5)(η5-C9H7)(C6H5)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Zr(η5-C5H5)(η5-C9H7)(C6H5)2]

There total 1 articles about [Zr(η5-C5H5)(η5-C9H7)(C6H5)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

(η5-cyclopentadienyl)(η5-indenyl) zirconium(IV) dichloride (80155-52-8) + phenylmagnesium chloride (100-59-4) → [Zr(η5-C5H5)(η5-C9H7)(C6H5)2] (301336-68-5)

Guidance literature:

In tetrahydrofuran; diethyl ether; Ar; dropwise addn. of PhMgCl in THF to a suspn. of Zr complex in Et2O at -78°C under stirring, mixt. stirred in absence of light and allowed to warm to room temp. in 10 h; solvent removed under reduced pressure, dry activated charcoal added; mixt. extd. with toluene, stirred for 1 h, filtered, filtrate concd., pentane added, cooled to -18°C for 24 h, ppt. washed with pentane;

DOI:10.1016/S0022-328X(00)00253-9

Reference yield: 52.0%

(η5-cyclopentadienyl)(η5-indenyl) zirconium(IV) dichloride (80155-52-8) + [Zr(η5-C5H5)(η5-C9H7)(C6H5)2] (301336-68-5) → [Zr(η5-C5H5)(η5-C9H7)(C6H5)Cl] (207917-43-9)

Guidance literature:

With LiCl; In tetrahydrofuran; Ar atmosphere; addn. of THF to C14H12Cl2Zr, C26H22Zr and LiCl at room temp., mixt. stirred at 40°C in the absence of light for 15 h; solvent removed under reduced pressure, pentane added, suspn. stirred at 40°C for 1 h, filtered, concd., cooled to -18°C for 64 h, ppt.;

DOI:10.1016/S0022-328X(00)00253-9

Reference yield:

(+)-β-chlorodiisopinocampheylborane + [Zr(η5-C5H5)(η5-C9H7)(C6H5)2] (301336-68-5) → [Zr(η5-C5H5)(η5-C9H7)(C6H5)Cl] (207917-43-9) + (C10H17)2BC6H5

Guidance literature:

In toluene; to toluene soln. of C26H22Zr toluene soln. of (C10H17)2BCl was added, stirred overnight; solvent removed in vac., C20H17ClZr not isolated, detected by NMR;

DOI:10.1016/S0022-328X(00)00253-9

upstream raw materials:

(η5-cyclopentadienyl)(η5-indenyl) zirconium(IV) dichloride

phenylmagnesium chloride

Downstream raw materials:

[Zr(η5-C5H5)(η5-C9H7)(C6H5)Cl]

Refernces