(1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime

Base Information

• Chemical Name: (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime
• CAS No.: 4736-14-5
• Molecular Formula: C₈H₁₃NO
• Molecular Weight: 139.197
• Mol file: 4736-14-5.mol

Synonyms:

Chemical Property of (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime

There total 4 articles about (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-methyl-4-formylcyclohexene (17775-58-5) → 2-Methyl-3-cyclohexenal-oxim (4736-14-5,112710-11-9,112710-12-0)

Guidance literature:

With hydroxylamine hydrochloride; sodium carbonate; In benzene; at 80 ℃; for 5h;

DOI:10.1080/00304949809355279

Reference yield:

2-methyl-3-cyclohexene-1-carboxaldehyde (873-30-3) → (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime (4736-14-5,112710-11-9,112710-12-0) + (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime (4736-14-5,112710-11-9,112710-12-0)

Guidance literature:

With hydroxylamine hydrochloride; sodium carbonate; In ethanol; water; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/jo00240a006

Reference yield:

2-methyl-3-cyclohexene-1-carboxaldehyde (873-30-3) → (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime (4736-14-5,112710-11-9,112710-12-0) + (1R,2S)-2-Methyl-cyclohex-3-enecarbaldehyde oxime (4736-14-5,112710-11-9,112710-12-0)

Guidance literature:

With hydroxylamine hydrochloride; sodium carbonate; In ethanol; water; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/jo00240a006

upstream raw materials:

2-methyl-3-cyclohexene-1-carboxaldehyde

3-methyl-4-formylcyclohexene

Downstream raw materials:

1-<(N-(methoxycarbonyl)amino)methylene>-2-methyl-3-cyclohexene

1-<(N-(methoxycarbonyl)amino)methylene>-2-methyl-3-cyclohexene

N,O-bis(methoxycarbonyl)-N-<(2-methyl-3-cyclohexenyl)methyl>hydroxylamine

Refernces

• 1、 Gueler, Ersin,Sen, Nejdet,Sirit, Abdulkadir,Kurbanov, Sultan,Mirzaoglu, Ramazan. "Investigation of the alkylation of aromatic and hydroaromatic aldoximes with halohydrins". . p. 195 - 202. Retrieved 2007/10/03.