Mes2B[(η6-Mes)FeCp][PF6]

Base Information

• Chemical Name: Mes2B[(η6-Mes)FeCp][PF6]
• CAS No.: 1340017-99-3
• Molecular Formula: C₃₂H₃₈BFe*F₆P
• Molecular Weight: 634.276
• Mol file: 1340017-99-3.mol

Synonyms:

Chemical Property of Mes2B[(η6-Mes)FeCp][PF6]

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mes2B[(η6-Mes)FeCp][PF6]

There total 1 articles about Mes2B[(η6-Mes)FeCp][PF6] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

η6-(naphtalene)(η5-cyclopentadienyl)-iron(II) hexafluorophosphate + trimesitylborane (7297-95-2) → Mes2B[(η6-Mes)FeCp][PF6] (1340017-99-3)

Guidance literature:

In further solvent(s); (N2) Fe complex was added to soln. trimesitylborane in 1,3-dichloropropane, heated to reflux for 1.5 h; react. mixt. was cooled to room temp., CHCl3 was added, soln. was filtered, hexane was added, ppt. was recrystd. by hexane diffusion into CHCl3 soln.; elem. anal.;

DOI:10.1039/c1nj20290a

Reference yield: 70.0%

potassium fluoride (7789-23-3) + Mes2B[(η6-Mes)FeCp][PF6] (1340017-99-3) → ((C5H5)Fe((CH3)3C6H2BF(C6H2(CH3)3)2)) (1340018-00-9)

Guidance literature:

In methanol; ppt. was filtered; elem. anal.;

DOI:10.1039/c1nj20290a

Reference yield: 70.0%

potassium cyanide + chloroform (67-66-3,8013-54-5) + Mes2B[(η6-Mes)FeCp][PF6] (1340017-99-3) → ((C5H5)Fe((CH3)3C6H2BCN(C6H2(CH3)3)2))*0.75CHCl3

Guidance literature:

In methanol; ppt. was filtered; elem. anal.;

DOI:10.1039/c1nj20290a

upstream raw materials:

trimesitylborane

Downstream raw materials:

((C₅H₅)Fe((CH₃)3C₆H₂BF(C₆H₂(CH₃)3)2))

Refernces