1-Butyl-3-methylimidazolium dicyanamide

Base Information

• Chemical Name: 1-Butyl-3-methylimidazolium dicyanamide
• CAS No.: 448245-52-1
• Molecular Formula: C10H15N5
• Molecular Weight: 205.263
• Hs Code.: 29332900
• European Community (EC) Number: 628-456-1
• DSSTox Substance ID: DTXSID9047910
• ChEMBL ID: CHEMBL3182985
• Mol file: 448245-52-1.mol

Synonyms:1-Butyl-3-methylimidazolium dicyanamide;448245-52-1;1-Butyl-3-methyl-3-imidazolium Di(cyano)amide;DTXSID9047910;MFCD07784457;1-butyl-3-methylimidazol-3-ium;cyanoiminomethylideneazanide;1-Butyl-3-Methylimidazolium Dicyamide;[bmim][dca];SCHEMBL1956577;CHEMBL3182985;DTXCID2027886;Tox21_200587;AC7816;1-Butyl-3-methylimidazoliumdicyanamide;AKOS005145836;NCGC00248748-01;NCGC00258141-01;AS-63157;SY039367;B5447;CAS-448245-52-1;CS-0186325;FT-0765103;A912496;1-butyl-3-methyl-1H-imidazol-3-ium;dicyanoazanide;Q-102661;1-BUTYL-3-METHYLIMIDAZOLIUM DICYANAMIDE [BMIm]N(CN)2

Chemical Property of 1-Butyl-3-methylimidazolium dicyanamide

Chemical Property:

• Melting Point: -6°C(lit.)
• Refractive Index: 1.5080 to 1.5120
• PSA: 56.39000
• Density: 1.06 g/cm3
• LogP: 1.43496
• Storage Temp.: Store at +15°C to +25°C.
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 205.13274550
• Heavy Atom Count: 15
• Complexity: 179

Purity/Quality:

99% ^*data from raw suppliers

1-Butyl-3-methylimidazolium dicyanamide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCN1C=C[N+](=C1)C.C(=[N-])=NC#N
• Uses: 1-Butyl-3-methylimidazolium Dicyanamide is used in preparation method of Carbon-supported alkaline Ionic liquid-metal catalyst and its application in catalytic transfer Hydrogenation of Azo intermediate to produce UV absorber Benzotriazole.

Technology Process of 1-Butyl-3-methylimidazolium dicyanamide

There total 6 articles about 1-Butyl-3-methylimidazolium dicyanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

sodium dicyanamide (1934-75-4) + 1-n-butyl-3-methylimidazolim bromide (85100-77-2) → 1-buthyl-3-methylimidazolium dicyanamide (448245-52-1)

Guidance literature:

In acetone; at 20 ℃; for 2h;

DOI:10.1016/j.electacta.2021.137865

Reference yield: 96.0%

sodium dicyanamide (1934-75-4) + 1-butyl-3-methylimidazolium chloride (79917-90-1) → 1-buthyl-3-methylimidazolium dicyanamide (448245-52-1)

Guidance literature:

In dichloromethane; at 20 ℃; for 48h;

DOI:10.1007/s10847-009-9600-3

Reference yield: 91.0%

silver dicyanamide (51342-29-1) + 1-n-butyl-3-methylimidazolim bromide (85100-77-2) → 1-buthyl-3-methylimidazolium dicyanamide (448245-52-1)

Guidance literature:

In water; at 20 ℃; Darkness;

DOI:10.1246/cl.151169

upstream raw materials:

sodium dicyanamide

1-n-butyl-3-methylimidazolim bromide

1-butyl-3-methylimidazolium chloride

silver dicyanamide

Downstream raw materials:

2,4,6-triamino-s-triazine

CYANAMID

N-cyanourea

[BMIM]N[(CN)B(C₆F₅)3]2

Refernces

• 1、 Guglielmero,Langroudi, Mo. Meskinfam,Khatib, M. Al,de Oliveira, M. Aysla Costa,Mecheri,De Leo,Mezzetta,Guazzelli,Giglioli,Epifanio, A. D',Pogni,Chiappe,Pomelli. "Electrochemical and spectroscopic study of vanadyl acetylacetonate–ionic liquids interactions". . . Retrieved 2021/02/16.
• 2、 Hawker, Rebecca R.,Haines, Ronald S.,Harper, Jason B.. "The effect of varying the anion of an ionic liquid on the solvent effects on a nucleophilic aromatic substitution reaction". supporting information. p. 3453 - 3463. Retrieved 2018/05/23.