C₃₄H₃₁ClNO₂PPd

Base Information

• Chemical Name: C₃₄H₃₁ClNO₂PPd
• CAS No.: 1417598-25-4
• Molecular Formula: C₃₄H₃₁ClNO₂PPd
• Molecular Weight: 658.472
• Mol file: 1417598-25-4.mol

Synonyms:

Chemical Property of C₃₄H₃₁ClNO₂PPd

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₄H₃₁ClNO₂PPd

There total 4 articles about C₃₄H₃₁ClNO₂PPd which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

palladium diacetate (3375-31-3) + methyl 2-amino-2,3-diphenylpropanoate (118783-29-2) + triphenylphosphine (603-35-0) + lithium chloride → C34H31ClNO2PPd (1417598-25-4) + C34H31ClNO2PPd (1417598-32-3)

Guidance literature:

palladium diacetate; methyl 2-amino-2,3-diphenylpropanoate; In toluene; at 80 ℃; for 22h;

triphenylphosphine; lithium chloride; In acetone; at 20 ℃; for 1h;

DOI:10.1021/om301140t

Reference yield:

C23H20ClNO2 (1417598-22-1) → C34H31ClNO2PPd (1417598-25-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: hydrogenchloride; water / toluene / 2 h / 20 °C

2.1: toluene / 22 h / 80 °C

2.2: 1 h / 20 °C

With hydrogenchloride; water; In toluene;

DOI:10.1021/om301140t

Reference yield:

methyl N-p-chlorobenzylidene(phenyl)glycinate (75984-69-9) → C34H31ClNO2PPd (1417598-25-4)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium hydroxide; potassium carbonate; tetrabutyl-ammonium chloride / dichloromethane; water / 96 h / 20 °C

2.1: hydrogenchloride; water / toluene / 2 h / 20 °C

3.1: toluene / 22 h / 80 °C

3.2: 1 h / 20 °C

With hydrogenchloride; tetrabutyl-ammonium chloride; water; potassium carbonate; potassium hydroxide; In dichloromethane; water; toluene;

DOI:10.1021/om301140t

upstream raw materials:

methyl N-p-chlorobenzylidene(phenyl)glycinate

C₂₃H₂₀ClNO₂

palladium diacetate

methyl 2-amino-2,3-diphenylpropanoate

Refernces