tetracarbonyl(η2-(1-(diphenylphosphino)-2-(diethylamino)ethane))molybdenium

Base Information

• Chemical Name: tetracarbonyl(η2-(1-(diphenylphosphino)-2-(diethylamino)ethane))molybdenium
• CAS No.: 86273-15-6
• Molecular Formula: C₂₂H₂₄MoNO₄P
• Molecular Weight: 493.351
• Mol file: 86273-15-6.mol

Synonyms:

Chemical Property of tetracarbonyl(η2-(1-(diphenylphosphino)-2-(diethylamino)ethane))molybdenium

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tetracarbonyl(η2-(1-(diphenylphosphino)-2-(diethylamino)ethane))molybdenium

There total 1 articles about tetracarbonyl(η2-(1-(diphenylphosphino)-2-(diethylamino)ethane))molybdenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetracarbonyl(η1-1-diethylamino-2-diphenylphosphinoethane)molibdenum(0) → (1-(diethylamino)-2-(diphenylphosphino)ethane)tetracarbonylmolybdenum (14971-44-9,86273-15-6)

Guidance literature:

In 1,2-dichloro-ethane; chelate ring reclosure in (η1-Ph2P(CH2)2NEt2)Mo(CO)4 obtained by pulse laser flash photolysis of the corresponding η2-complex under N2 was monitored by UV spectroscopy; rate const. is given; Kinetics;

DOI:10.1016/S0022-328X(00)99238-6

Reference yield:

(1-(diethylamino)-2-(diphenylphosphino)ethane)tetracarbonylmolybdenum (14971-44-9,86273-15-6) → (1-(diethylamino)-2-(diphenylphosphino)ethane)(triphenylphosphine)tetracarbonylmolybdenum

Guidance literature:

With triphenylphosphine; In chlorobenzene; Irradiation (UV/VIS); flash photolysis at 24.6°C; monitored by IR, rate consts. given; Kinetics;

DOI:10.1021/ja00289a001

Reference yield:

(1-(diethylamino)-2-(diphenylphosphino)ethane)tetracarbonylmolybdenum (14971-44-9,86273-15-6) + tributylphosphine (998-40-3) → (1-(diethylamino)-2-(diphenylphosphino)ethane)(tri-n-butylphosphine)tetracarbonylmolybdenum

Guidance literature:

With triphenylphosphine; In chlorobenzene; Irradiation (UV/VIS); flash photolysis at 24.6°C; monitored by IR, rate consts. given; Kinetics;

DOI:10.1021/ja00289a001

Downstream raw materials:

cis-(1-(diethylamino)-2-(diphenylphosphino)ethane)(triisopropylphosphite)tetracarbonylmolybdenum

Refernces