(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II)

Base Information

• Chemical Name: (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II)
• CAS No.: 143006-27-3
• Molecular Formula: C₂₆H₄Cl₂F₂₀P₂Pt
• Molecular Weight: 1024.22
• Mol file: 143006-27-3.mol

Synonyms:

Chemical Property of (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II)

There total 2 articles about (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,2-bis(di(pentafluorophenyl)phosphino)ethane (76858-94-1) → (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II) (143006-27-3)

Guidance literature:

In toluene; according to Merwin R. K., et al., Organometallics, 1992, 11, 2972; (Ar); soln. of ligand and Pt complex in toluene was stirred under reflux for12 h; cooled to room temp.; filtered; washed with Et2O in air;

DOI:10.1021/om100073j

Reference yield: 83.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,2-bis(di(pentafluorophenyl)phosphino)ethane (76858-94-1) → (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II) (143006-27-3)

Guidance literature:

In toluene; byproducts: cyclooctadiene; refluxing under N2, 24h; cooling to room temp.; pptn.; filtration; washing (ether); drying, 1d; elem. anal.;

Reference yield: 93.0%

silver tetrafluoroborate (14104-20-2) + (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)dichloroplatinum(II) (143006-27-3) + water (7732-18-5) → [Pt(μ-OH)(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)]2(BF4)2

Guidance literature:

In methanol; acetone; byproducts: AgCl; (N2); using Schlenk techniques; addn. of acetone soln. of AgBF4 (2 equiv.) to suspn. of PtCl2(1,2-bis(bis(2,3,4,5,6-pentafluorophenyl)phosphino)ethane) in wet methanol at room temp.; stirring for 2 h; filtration, concn., treatment with Et2O, filtration, drying under vac., elem. anal.;

DOI:10.1021/om049264a

upstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

1,2-bis(di(pentafluorophenyl)phosphino)ethane

dichloro( 1,5-cyclooctadiene)platinum(ll)

Downstream raw materials:

[PtCl(2,6-dimethylphenyl isocyanide)(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)](BF₄)

(dfppe)Pt(OTf)2

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

Refernces

• 1、 Michelin, Rino A.,Pizzo, Erika,Scarso, Alessandro,Sgarbossa, Paolo,Strukul, Giorgio,Tassan, Augusto. "Baeyer-Villiger oxidation of ketones catalyzed by platinum(II) lewis acid complexes containing coordinated electron-poor fluorinated diphosphines". . p. 1012 - 1017. Retrieved 2008/10/09.