Nonylmagnesium bromide

Base Information

• Chemical Name: Nonylmagnesium bromide
• CAS No.: 39691-62-8
• Molecular Formula: C9H19BrMg
• Molecular Weight: 231.459
• Hs Code.: 29319090
• European Community (EC) Number: 628-320-1
• Mol file: 39691-62-8.mol

Synonyms:nonylmagnesium bromide;39691-62-8;magnesium;nonane;bromide;MFCD03094048;n-Nonylmagnesium bromide, 0.50 M in 2-MeTHF;SCHEMBL570869;IFQPKTPQJLAZHQ-UHFFFAOYSA-M;AKOS016017745;Nonylmagnesium bromide, 0.5M in tetrahydrofuran

Chemical Property of Nonylmagnesium bromide

Chemical Property:

• Appearance/Colour: UN 2924
• Boiling Point: 35 °C
• Flash Point: -22 °F
• PSA: 0.00000
• Density: 0.849 g/mL at 25 °C
• LogP: 4.55020
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 230.05205
• Heavy Atom Count: 11
• Complexity: 48.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Nonylmagnesium bromide solution 1.0M in diethyl ether ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+,C
• Hazard Codes: F+,C
• Statements: 12-14-19-22-34-67
• Safety Statements: 9-16-29-33-45-36/37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCC[CH2-].[Mg+2].[Br-]

Technology Process of Nonylmagnesium bromide

There total 4 articles about Nonylmagnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromononane (693-58-3) + magnesium (7439-95-4) → nonylmagnesium bromide (39691-62-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/c4cc08826c

Reference yield:

1-Bromononane (693-58-3) → nonylmagnesium bromide (39691-62-8)

Guidance literature:

With magnesium; In diethyl ether; Thermodynamic data; -ΔH(reaction);

Reference yield:

1-Bromononane (693-58-3) → nonylmagnesium bromide (39691-62-8)

Guidance literature:

With diethyl ether;

upstream raw materials:

1-Bromononane

magnesium

Downstream raw materials:

2,4-dimethyltridecane

1-dodecene

(2S,3S,5R)-2-Benzyl-5-nonyl-3-[(R)-1-(2,4,6-triisopropyl-phenyl)-ethoxy]-pyrrolidine-1-carboxylic acid tert-butyl ester

(4S,5S)-2,2-dimethyl-3-(tert-butoxycarbonyl)-4-benzyl-5-(2-hydroxyundecyl)-1,3-oxazolidine

Refernces

• 1、 -. "Method for producing alkyl-bridged ligand systems and transition metal compounds". . . Retrieved 2008/06/13.
• 2、 Holm, Torkil. "Thermochemical Bond Dissociation Energies of Carbon-Magnesium Bonds". . p. 464 - 467. Retrieved 2007/10/02.