[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride

Base Information

• Chemical Name: [Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
• CAS No.: 915299-24-0
• Molecular Formula: C42H63AuClO3P
• Molecular Weight: 879.354
• Mol file: 915299-24-0.mol

Synonyms:[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride;Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold

Chemical Property of [Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride

Chemical Property:

• Melting Point: 200-202 °C
• PSA: 41.28000
• LogP: 10.23680
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

98.5% ^*data from raw suppliers

Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of [Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride

There total 5 articles about [Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

hydrogen tetrachloroaurate(III) tetrahydrate + tris(4-(tert-butyl)phenyl) phosphite (4235-89-6) → tris(2,4-di-tert-butylphenyl)phosphite gold(I) chloride (915299-24-0)

Guidance literature:

hydrogen tetrachloroaurate(III) tetrahydrate; With propyl sulfide; In ethanol; at 40 ℃; for 0.166667h;

tri(p-tert-butylphenyl) phosphite; In ethanol; at 40 ℃; for 1h;

DOI:10.1021/ja311258e

Reference yield: 94.0%

sodium tetrachloroaurate(III) dihyrate + tris(2,4-di-tert-butylphenyl)phosphite (31570-04-4) → tris(2,4-di-tert-butylphenyl)phosphite gold(I) chloride (915299-24-0)

Guidance literature:

sodium tetrachloroaurate(III) dihyrate; With 2,2'-thiobis-ethanol; In water; for 0.75h; Cooling with ice;

tris(2,4-di-tert-butylphenyl)phosphite; In ethanol; water;

DOI:10.1016/j.tet.2016.03.020

Reference yield: 93.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + tris(2,4-di-tert-butylphenyl)phosphite (31570-04-4) → tris(2,4-di-tert-butylphenyl)phosphite gold(I) chloride (915299-24-0)

Guidance literature:

In dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/d0cc06978g

upstream raw materials:

tris(4-(tert-butyl)phenyl) phosphite

chloro(dimethylsulfide) gold(I)

tris(2,4-di-tert-butylphenyl)phosphite

(tetrahydrothiophene)gold(I) chloride

Refernces

• 1、 Theulier, Cyril A.,García-Rodeja, Yago,Saffon-Merceron, Nathalie,Miqueu, Karinne,Bouhadir, Ghenwa,Bourissou, Didier. "1,1-Phosphaboration of CC and CC bonds at gold". supporting information. p. 347 - 350. Retrieved 2021/01/25.
• 2、 Pérez-Galán, Patricia,Waldmann, Herbert,Kumar, Kamal. "Building polycyclic indole scaffolds via gold(I)-catalyzed intra- and inter-molecular cyclization reactions of 1,6-enynes". supporting information. p. 3647 - 3652. Retrieved 2016/06/06.