1-O-β-D-cellobiopyranosyl hydroquinone

Base Information

• Chemical Name: 1-O-β-D-cellobiopyranosyl hydroquinone
• CAS No.: 7013-26-5
• Molecular Formula: C₁₈H₂₆O₁₂
• Molecular Weight: 434.397
• Mol file: 7013-26-5.mol

Synonyms:

Chemical Property of 1-O-β-D-cellobiopyranosyl hydroquinone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O-β-D-cellobiopyranosyl hydroquinone

There total 3 articles about 1-O-β-D-cellobiopyranosyl hydroquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.8%

α-D-glucopyranosyl-1-phosphate (59-56-3,27251-84-9,63779-58-8,262856-84-8) + arbutin (497-76-7) → 1-O-β-D-cellotriopyranosyl hydroquinone + 1-O-β-D-cellobiopyranosyl hydroquinone (7013-26-5)

Guidance literature:

With recombinant cellodextrin phosphorylase from Clostridium stercocarium; In ethyl acetate; at 37 ℃; for 48h; pH=6.5; Enzymatic reaction;

DOI:10.1021/acs.jafc.5b04380

Reference yield:

hydroquinone (123-31-9,8027-02-9) + α-D-glucopyranosyl-1-phosphate (59-56-3,27251-84-9,63779-58-8,262856-84-8) → 1-O-β-D-cellobiopyranosyl hydroquinone (7013-26-5)

Guidance literature:

Multi-step reaction with 2 steps

1: recombinant cellobiosephosphorylase from C_. thermocellum / ethyl acetate / 48 h / 50 °C / pH 6.5 / Enzymatic reaction

2: recombinant cellodextrin phosphorylase from Clostridium stercocarium / ethyl acetate / 48 h / 37 °C / pH 6.5 / Enzymatic reaction

With recombinant cellobiosephosphorylase from C_. thermocellum; recombinant cellodextrin phosphorylase from Clostridium stercocarium; In ethyl acetate;

DOI:10.1021/acs.jafc.5b04380

Reference yield:

→ 1-O-β-D-cellobiopyranosyl hydroquinone (7013-26-5)

Guidance literature:

With methanol; sodium methylate;

upstream raw materials:

α-D-glucopyranosyl-1-phosphate

arbutin

hydroquinone

Refernces