4-Dibenzofuranamine

Base Information

• Chemical Name: 4-Dibenzofuranamine
• CAS No.: 50548-43-1
• Molecular Formula: C12H9NO
• Molecular Weight: 183.21
• Hs Code.: 2932999099
• European Community (EC) Number: 835-946-0
• DSSTox Substance ID: DTXSID80332639
• Nikkaji Number: J89.561J
• Wikidata: Q72435588
• Mol file: 50548-43-1.mol

Synonyms:4-Dibenzofuranamine;50548-43-1;dibenzofuran-4-amine;4-Aminodibenzofuran;Dibenzo[b,d]furan-4-amine;4-Dibenzo[b]furanamine;Dibenzo[b,d]furan-4-amine #;SCHEMBL2342912;1-Isopropyl-4-(vinyloxy)benzene;AMY8759;DTXSID80332639;MFCD11110988;AKOS006306679;DS-11551;A7493;CS-0112415;D5520;FT-0728847;C75368;8-oxatricyclo[7.4.0.0?,?]trideca-1(9),2(7),3,5,10,12-hexaen-6-amine

Chemical Property of 4-Dibenzofuranamine

Chemical Property:

• Vapor Pressure: 1.21E-05mmHg at 25°C
• Melting Point: 113.5-114.5℃
• Refractive Index: 1.755
• Boiling Point: 369.1 °C at 760 mmHg
• PKA: 3.51±0.30(Predicted)
• Flash Point: 177 °C
• PSA: 39.16000
• Density: 1.283 g/cm³
• LogP: 3.74940
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 183.068413911
• Heavy Atom Count: 14
• Complexity: 218

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dibenzo[b,d]furan-4-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=C(O2)C(=CC=C3)N

Technology Process of 4-Dibenzofuranamine

There total 22 articles about 4-Dibenzofuranamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.6%

4-nitrosodibenzo[b,d]furan (1374116-16-1) → 4-aminodibenzofuran (50548-43-1)

Guidance literature:

With iron⁽⁰⁾; acetic acid; at 60 ℃; for 12h; under 760.051 Torr; Reagent/catalyst;

Reference yield: 92.0%

4-dibenzofurylboronic acid (100124-06-9) → 4-aminodibenzofuran (50548-43-1)

Guidance literature:

With copper oxide (I); ammonium hydroxide; air; In methanol; at 20 ℃; for 15h;

DOI:10.1002/anie.200805424

Reference yield: 92.0%

N-(4-dibenzofuranyl)acetamide (50548-37-3) → 4-aminodibenzofuran (50548-43-1) + 1,3-dibromodibenzo[b,d]furan-4-amine (1332882-09-3)

Guidance literature:

With hydrogenchloride; In methanol; 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran;

upstream raw materials:

O-Methylhydroxylamin

dibenzofuran

4-hydroxydibenzofuran

3,3'-Diiododiphenylene oxide

Downstream raw materials:

1-(1,3-diisopropyldibenzo[b,d]furan-4-yl)-2-phenyl-4,5-dihydro-1H-imidazole

1-(1,3-diisopropyldibenzo[b,d]furan-4-yl)-2-phenyl-1H-imidazole

N-(4-(tert-butyl)phenyl)dibenzo[b,d]furan-4-amine

Refernces

• 1、 Prakasham,Vigalok, Arkadi,Vedernikov, Andrei N.. "Synthesis and Bond Activation Chemistry of Palladium(II) Pincer Complexes with a Weakly Coordinating Side Arm". supporting information. p. 634 - 641. Retrieved 2022/03/02.
• 2、 -. "ARYLAMINE DERIVATIVES, HOLE TRANSPORT MATERIAL COMPRISING THE SAME AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME". Paragraph 0067; 0073-0077. . Retrieved 2020/10/22.