(propene-2 oate de methyle) yl-4 cyclohexene cis

Base Information

• Chemical Name: (propene-2 oate de methyle) yl-4 cyclohexene cis
• CAS No.: 120264-02-0
• Molecular Formula: C₁₀H₁₄O₂
• Molecular Weight: 166.22
• Mol file: 120264-02-0.mol

Synonyms:

Chemical Property of (propene-2 oate de methyle) yl-4 cyclohexene cis

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (propene-2 oate de methyle) yl-4 cyclohexene cis

There total 3 articles about (propene-2 oate de methyle) yl-4 cyclohexene cis which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethyl phosphonoacetate (5927-18-4) + 3-Cyclohexene-1-carboxaldehyde (100-50-5,61746-36-9) → (propene-2 oate de methyle) yl-4 cyclohexene trans (124939-60-2) + (propene-2 oate de methyle) yl-4 cyclohexene cis (120264-02-0)

Guidance literature:

With sodium hydride; In 1,2-dimethoxyethane; at 10 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/0022-328X(89)88097-0

Reference yield:

3-(cyclohex-3-en-1-yl)propanoic acid (22482-62-8) → (propene-2 oate de methyle) yl-4 cyclohexene cis (120264-02-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 79 percent / p-TsOH / CCl₄ / 8 h / Heating

With toluene-4-sulfonic acid; In tetrachloromethane;

Reference yield:

3-(3-Cyclohexen-1-yl)propansaeure-methylester (78640-15-0) + formic acid ethyl ester (109-94-4) → (propene-2 oate de methyle) yl-4 cyclohexene cis (120264-02-0) + Tricyclo<3.2.1.02,7>octan-1-carbonsaeure-methylester (120264-03-1)

Guidance literature:

Yield given. Multistep reaction. Yields of byproduct given;

upstream raw materials:

trimethyl phosphonoacetate

3-Cyclohexene-1-carboxaldehyde

3-(3-Cyclohexen-1-yl)propansaeure-methylester

formic acid ethyl ester

Refernces

• 1、 Kirmse, Wolfgang,Feldmann, Georg. "Deamination Reactions, 53. - Bridgehead Alkenes from Tricyclic Diazonium Ions". . p. 1531 - 1544. Retrieved 2007/10/02.