cis-bis(isothiocycanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid)-(2,2'-bipyridyl-4,4'-dinonyl) rutheniuM(II)

Base Information

• Chemical Name: cis-bis(isothiocycanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid)-(2,2'-bipyridyl-4,4'-dinonyl) rutheniuM(II)
• CAS No.: 502693-09-6
• Molecular Formula: C42H52N6O4RuS2
• Molecular Weight: 870.10
• Hs Code.: 28439000
• Mol file: 502693-09-6.mol

Synonyms:Z907

Chemical Property of cis-bis(isothiocycanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid)-(2,2'-bipyridyl-4,4'-dinonyl) rutheniuM(II)

Chemical Property:

• Melting Point: 196 °C

• PSA: 190.34000
• LogP: 11.58700
• Solubility.: Acetonitrile/tert-butanol (v/v = 1:1); DMSO

Purity/Quality:

98% ^*data from raw suppliers

Bis(isothiocyanato)(2,2'-bipyridyl-4,4'-dicarboxylato)(4,4'-dinonyl-2,2'-bipyridyl)ruthenium(II) >80.0%(HPLC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-43
• Safety Statements: 26-36/37

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Description: Z-907 dye, (cis-Ru(H2dcbpy)(dnbpy)(NCS)2, where the ligand H2dcbpy?is 4,4′-dicarboxylic acid-2, 2′-bipyridine and dnbpy is 4,4′-dinonyl-2,2′-bipyridine, is amphiphilic nature while the introduction of the two hydrophobic alkyl chains on the bipyridyl ligand is critical to provide an insulating barrier to avoid charge carrier recombination and also help enhance?thermal stability.
• Uses: High-performance ruthenium-based dye used in dye-sensitized solar cells (DSCs) for the sensitization of Titania. Hydrophobic character due to the presence of C9 alkyl chains.

Technology Process of cis-bis(isothiocycanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid)-(2,2'-bipyridyl-4,4'-dinonyl) rutheniuM(II)

There total 2 articles about cis-bis(isothiocycanato)-(2,2'-bipyridyl-4,4'-dicarboxylic acid)-(2,2'-bipyridyl-4,4'-dinonyl) rutheniuM(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

ruthenium(III) chloride trihydrate + 2,2'-Bipyridine-4,4'-dicarboxylic acid (6813-38-3) + ammonium thiocyanate + 4,4'-dinonyl-2,2'-bipyridine (142646-58-0) → Z907 (502693-09-6)

Guidance literature:

ruthenium(III) chloride trihydrate; 2,2'-Bipyridine-4,4'-dicarboxylic acid; 4,4'-dinonyl-2,2'-bipyridine; In 1-methyl-pyrrolidin-2-one; at 140 - 150 ℃; for 1.5h;

ammonium thiocyanate; In 1-methyl-pyrrolidin-2-one; for 1h; Solvent;

Reference yield: 28.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 2,2'-Bipyridine-4,4'-dicarboxylic acid (6813-38-3) + ammonium thiocyanate + 4,4'-dinonyl-2,2'-bipyridine (142646-58-0) → Z907 (502693-09-6)

Guidance literature:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; 2,2'-Bipyridine-4,4'-dicarboxylic acid; 4,4'-dinonyl-2,2'-bipyridine; In 1-methyl-pyrrolidin-2-one; at 140 - 150 ℃; for 1.5h;

ammonium thiocyanate; In 1-methyl-pyrrolidin-2-one; for 1h; Solvent;

upstream raw materials:

2,2'-Bipyridine-4,4'-dicarboxylic acid

4,4'-dinonyl-2,2'-bipyridine

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

Refernces