geranyl mesitoate

Base Information

• Chemical Name: geranyl mesitoate
• CAS No.: 1674-04-0
• Molecular Formula: C₂₀H₂₈O₂
• Molecular Weight: 300.441
• Mol file: 1674-04-0.mol

Synonyms:

Chemical Property of geranyl mesitoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of geranyl mesitoate

There total 1 articles about geranyl mesitoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Geraniol (106-24-1) + mesitylene-2-carboxylic acid chloride (938-18-1) → geranyl mesitoate (1674-04-0)

Guidance literature:

With pyridine; In diethyl ether; at 0 ℃; for 2h;

DOI:10.1021/jo00942a027

Reference yield: 30.0%

geranyl mesitoate (1674-04-0) → 2,4,6-Trimethyl-benzoic acid (2E,6E)-8-hydroxy-3,7-dimethyl-octa-2,6-dienyl ester (79421-80-0)

Guidance literature:

With tert.-butylhydroperoxide; selenium(IV) oxide; salicylic acid; In dichloromethane; for 27h; Ambient temperature;

DOI:10.1016/0031-9422(81)85150-3

Reference yield:

geranyl mesitoate (1674-04-0) → 2,4,6-Trimethyl-benzoic acid (2E,6E)-8-bromo-3,7-dimethyl-octa-2,6-dienyl ester (79421-81-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 30 percent / SeO₂, salicylic acid, 90 percent t-butylhydroperoxide / CH₂Cl₂ / 27 h / Ambient temperature

2: PBr₃ / diethyl ether / 4 h / 0 °C

With tert.-butylhydroperoxide; selenium(IV) oxide; phosphorus tribromide; salicylic acid; In diethyl ether; dichloromethane;

DOI:10.1016/0031-9422(81)85150-3

upstream raw materials:

Geraniol

mesitylene-2-carboxylic acid chloride

Downstream raw materials:

(E)-6-Mesitoyloxy-4-methyl-4-hexenal

2,4,6-Trimethyl-benzoic acid (2E,6E)-3,7-dimethyl-8-oxo-octa-2,6-dienyl ester

2,4,6-Trimethyl-benzoic acid (2E,6E)-8-hydroxy-3,7-dimethyl-octa-2,6-dienyl ester

2,4,6-Trimethyl-benzoic acid (2E,6E)-8-bromo-3,7-dimethyl-octa-2,6-dienyl ester