4-Vinylbenzyl glycidyl ether

Base Information

• Chemical Name: 4-Vinylbenzyl glycidyl ether
• CAS No.: 113538-80-0
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• DSSTox Substance ID: DTXSID30474058
• Nikkaji Number: J686.453H
• Mol file: 113538-80-0.mol

Synonyms:4-Vinylbenzyl glycidyl ether;113538-80-0;2-[(4-ethenylphenyl)methoxymethyl]oxirane;2-(((4-vinylbenzyl)oxy)methyl)oxirane;2-{[(4-ETHENYLPHENYL)METHOXY]METHYL}OXIRANE;4-Vinylbenzylglycidylether;2-((4-vinylbenzyloxy)methyl)oxirane;p-vinylbenzyl glycidyl ether;SCHEMBL239227;AMY2720;DTXSID30474058;ZADXFVHUPXKZBJ-UHFFFAOYSA-N;MFCD00674039;AKOS015917401;FT-0657406;A803065

Chemical Property of 4-Vinylbenzyl glycidyl ether

Chemical Property:

• Boiling Point: 299.221 °C at 760 mmHg
• Flash Point: 121.095 °C
• PSA: 21.76000
• Density: 1.088g/cm³
• LogP: 2.24500
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 190.099379685
• Heavy Atom Count: 14
• Complexity: 183

Purity/Quality:

95% ^*data from raw suppliers

4-Vinylbenzylglycidylether 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC1=CC=C(C=C1)COCC2CO2

Technology Process of 4-Vinylbenzyl glycidyl ether

There total 2 articles about 4-Vinylbenzyl glycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

4-Vinylbenzyl chloride (1592-20-7,29296-32-0) + oxiranyl-methanol (556-52-5) → 2-(4-vinyl-benzyloxymethyl)-oxirane (113538-80-0)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 4h;

DOI:10.1002/anie.201501795

Reference yield:

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) → 2-(4-vinyl-benzyloxymethyl)-oxirane (113538-80-0)

Guidance literature:

In toluene;

Reference yield: 90.0%

1,4-bis(dimethylsilyl)benzene (2488-01-9) + 2-(4-vinyl-benzyloxymethyl)-oxirane (113538-80-0) → 1,4-bis(dimethyl(4-((oxiran-2-ylmethoxy)methyl)phenethyl)silyl)benzene

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; In 5,5-dimethyl-1,3-cyclohexadiene; at 0 - 20 ℃; for 3.16667h; Inert atmosphere;

DOI:10.1016/j.polymer.2016.09.043

upstream raw materials:

styrene

4-Vinylbenzyl chloride

oxiranyl-methanol

Downstream raw materials:

4-vinylbenzyl 1,3-oxathiolane-2-thione-5-ylmethyl ether

C₁₆H₂₀O₄

C₁₈H₂₄O₄

Refernces

• 1、 Miyamura, Hiroyuki,Min, Hyemin,Soulé, Jean-Fran?ois,Kobayashi, Shu. "Size of gold nanoparticles driving selective amide synthesis through aerobic condensation of aldehydes and amines". supporting information. p. 7564 - 7567. Retrieved 2015/06/25.
• 2、 Soule, Jean-Francois,Miyamura, Hiroyuki,Kobayashi, Shu. "Selective imine formation from alcohols and amines catalyzed by polymer incarcerated gold/palladium alloy nanoparticles with molecular oxygen as an oxidant". supporting information. p. 355 - 357. Retrieved 2013/02/23.