9-(4-Tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole

Base Information

• Chemical Name: 9-(4-Tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole
• CAS No.: 898546-82-2
• Molecular Formula: C₅₈H₄₉NSi₂
• Molecular Weight: 816.205
• DSSTox Substance ID: DTXSID80694860
• Nikkaji Number: J2.332.074F
• Wikidata: Q72504018
• Mol file: 898546-82-2.mol

Synonyms:898546-82-2;9-(4-TERT-BUTYLPHENYL)-3,6-BIS(TRIPHENYLSILYL)-9H-CARBAZOLE;CzSi;[9-(4-Tert-butylphenyl)-6-triphenylsilylcarbazol-3-yl]-triphenylsilane;9-(4-(tert-Butyl)phenyl)-3,6-bis(triphenylsilyl)-9H-carbazole;SCHEMBL1200222;DTXSID80694860;MFCD16619363;CS-0378798;9-(4-(t-butyl) phenyl)-3,6-bis(triphenylsilyl)-carbazole;9-(4-tert-Butylphenyl)-3,6-bis(triphenylsilyl)-9H?carbazole;9-(4-tert-Butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole (CzSi)

Chemical Property of 9-(4-Tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole

Chemical Property:

• Melting Point: 354 °C(Solv: chloroform (67-66-3); hexane (110-54-3))
• PSA: 4.93000
• Density: 1.05 g/cm³
• LogP: 8.83600
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 815.34035364
• Heavy Atom Count: 61
• Complexity: 1160

Purity/Quality:

99% ^*data from raw suppliers

9-(4-tert-Butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)C1=CC=C(C=C1)N2C3=C(C=C(C=C3)[Si](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6)C7=C2C=CC(=C7)[Si](C8=CC=CC=C8)(C9=CC=CC=C9)C1=CC=CC=C1
• Description: CzSi is known for its high triplet energy, wide band-gap, and high glass-transition temperature (Tg >131 °C). It is one of the most widely-used TADF host materials for blue electrophosphorescence.
• Uses: Carbazole-based host materials for blue electrophosphorescence.

Technology Process of 9-(4-Tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole

There total 1 articles about 9-(4-Tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,6-dibromo-9-(4-(tert-butyl)phenyl)-9H-carbazole (741293-42-5) + Triphenylsilyl chloride (76-86-8) → 9-(4-tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole (898546-82-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran;

upstream raw materials:

3,6-dibromo-9-(4-(tert-butyl)phenyl)-9H-carbazole

Triphenylsilyl chloride

Refernces