Secoxyloganin methyl ester

Base Information

• Chemical Name: Secoxyloganin methyl ester
• CAS No.: 74713-15-8
• Molecular Formula: C₁₈H₂₆O₁₁
• Molecular Weight: 418.398
• Mol file: 74713-15-8.mol

Synonyms:Secoxyloganin methyl ester;2H-Pyran-4-acetic acid, 3-ethenyl-2-(β-D-glucopyranosyloxy)-3,4-dihydro-5-(methoxycarbonyl)-, methyl ester, (2S,3R,4S)-;methyl (2S,3R,4S)-3-ethenyl-4-(2-methoxy-2-oxoethyl)-2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-3,4-dihydro-2H-pyran-5-carboxylate

Chemical Property of Secoxyloganin methyl ester

Chemical Property:

• Melting Point: 134 °C(Solv: chloroform (67-66-3))
• Boiling Point: 586.2±50.0 °C(Predicted)
• PKA: 12.81±0.70(Predicted)
• PSA: 161.21000
• Density: 1.42±0.1 g/cm3(Predicted)
• LogP: -1.80240

Purity/Quality:

98%min ^*data from raw suppliers

Secoxyloganinmethylester 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Secoxyloganin methyl ester

There total 1 articles about Secoxyloganin methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

austrosmoside → secologanoside dimethyl ester (74713-15-8) + (8Z)-ligstroside

Guidance literature:

With sodium methylate; Ambient temperature;

DOI:10.1016/S0031-9422(97)00994-1

Reference yield:

secologanoside dimethyl ester (74713-15-8) → (1R,2R,6R)-3-Formyl-6-hydroxy-2-methoxycarbonylmethyl-cyclohex-3-enecarboxylic acid methyl ester + (1R,2R,6S)-3-Formyl-6-hydroxy-2-methoxycarbonylmethyl-cyclohex-3-enecarboxylic acid methyl ester

Guidance literature:

With β-glucosidase; Yield given. Yields of byproduct given. Title compound not separated from byproducts; pH: 7;

DOI:10.1039/c39800000165

Refernces