(Z)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylamino)prop-2-en-1-one

Base Information

• Chemical Name: (Z)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylamino)prop-2-en-1-one
• CAS No.: 1198786-86-5
• Molecular Formula: C₂₁H₂₅NOS
• Molecular Weight: 339.502
• Mol file: 1198786-86-5.mol

Synonyms:

Chemical Property of (Z)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylamino)prop-2-en-1-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylamino)prop-2-en-1-one

There total 1 articles about (Z)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylamino)prop-2-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

2-propylsulfanylethylamine (36517-93-8) + 1,3-diphenyl-2-methylpropane-1,3-dione (1846-29-3) → (Z)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylamino)prop-2-en-1-one (1198786-86-5)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; for 72h; Azeotropic water removal;

DOI:10.1039/b910868h

Reference yield: 66.0%

(Z)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylamino)prop-2-en-1-one (1198786-86-5) + titanium tetrachloride (7550-45-0) → [(1Z,3E)-2-methyl-1,3-diphenyl-3-(2-(propylthio)ethylimino)prop-1-en-1-olate]Ti(IV)Cl3

Guidance literature:

With KH; In tetrahydrofuran; dichloromethane; (N2); to suspn. of KH in THF was added soln. of enamine in THF at -78°C, warmed to room temp. and stirred for 3 h, evapd. in vac., dissolved in CH2Cl2, this soln. was added to soln. of TiCl4 in CH2Cl2 at room temp., stirred for 16 h; solid was filtered, washed with CH2Cl2, combined organic solutions were concd. in vac., kept at -30°C for few days, solid was collected, elem. anal.;

DOI:10.1039/b910868h

upstream raw materials:

2-propylsulfanylethylamine

1,3-diphenyl-2-methylpropane-1,3-dione

Refernces