ACETOXIME BENZOATE

Base Information

• Chemical Name: ACETOXIME BENZOATE
• CAS No.: 942-89-2
• Molecular Formula: C10 H11 N O2
• Molecular Weight: 177.203
• Hs Code.: 2928000090
• Mol file: 942-89-2.mol

Synonyms:Acetone, O-benzoyloxime (6CI,7CI,8CI); Acetone oxime O-benzoate; Acetone oxime benzoate;

Chemical Property of ACETOXIME BENZOATE

Chemical Property:

• Melting Point: 46-48 °C(lit.)
• Boiling Point: 120 °C / 1.5mmHg
• Flash Point: 110oC
• PSA: 38.66000
• Density: 1.03g/cm3
• LogP: 2.23920

Purity/Quality:

98%,99%, ^*data from raw suppliers

Acetoxime Benzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ACETOXIME BENZOATE

There total 13 articles about ACETOXIME BENZOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

O,O'-dibenzoyl-2,3-bis(hydroxylamino)-2,3-dimethylbutane (82365-28-4) → Acetone O-benzoyloxime (942-89-2)

Guidance literature:

With tert-butylhypochlorite; potassium carbonate; In dichloromethane; 1.) -10 deg C, 1 h, 2.) 20 deg C, 10 h; further solvent;

DOI:10.1007/BF00948251

Reference yield: 65.5%

benzoic acid (65-85-0,8013-63-6) + acetone oxime (127-06-0) → Acetone O-benzoyloxime (942-89-2)

Guidance literature:

With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine; In acetonitrile; at 20 ℃; for 0.5h;

DOI:10.14233/ajchem.2014.16522

Reference yield: 60.0%

C10H11NO2Te (1236132-60-7) → Acetone O-benzoyloxime (942-89-2)

Guidance literature:

With silica gel; at 23 ℃; for 1h;

DOI:10.1080/10426501003769728

upstream raw materials:

benzoyl chloride

acetone oxime

O-Benzoylhydroxylamine

acetone

Downstream raw materials:

1,5-dimethyl-1H-tetrazole

(1S)-N-(1-methylethylidene)-1-phenylethylamine

Isopropylidene-((R)-1-phenyl-ethyl)-amine

1-hydroxy-1-phenyl-3-butanone

Refernces

• 1、 Nakaiida, Shoho,Kato, Shinzi,Niyomura, Osamu,Ishida, Masaru,Ando, Fumio,Koketsu, Jugo. "Te-1-acylmethyl and Te-1-iminoalkyl telluroesters: Synthesis and thermolysis leading to 1,3-diketones and O-alkenyl and O-imino esters". experimental part. p. 930 - 946. Retrieved 2010/08/04.
• 2、 Shustov, G. V.,Tavakalyan, N. B.,Shustova, L. L.,Pleshkova, A. P.,Kostyanovskii, R. G.. "OXIDATIVE CLEAVAGE OF VICINAL BIS(HYDROXYLAMINES)". . p. 330 - 339. Retrieved 2007/10/02.