1-bromopropylbenzene

Base Information

• Chemical Name: 1-bromopropylbenzene
• CAS No.: 2114-36-5
• Molecular Formula: C₉H₁₁Br
• Molecular Weight: 199.09
• Hs Code.: 2903999090
• Mol file: 2114-36-5.mol

Synonyms:4-bromopropylbenzene;phenylpropyl bromide;1-Bromo-1-phenylpropane;

Chemical Property of 1-bromopropylbenzene

Chemical Property:

• Boiling Point: 215.5 °C at 760 mmHg
• Flash Point: 92.5 °C
• PSA: 0.00000
• Density: 1.303 g/cm³
• LogP: 3.53260

Purity/Quality:

99.3% ^*data from raw suppliers

(1-Bromopropyl)benzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-bromopropylbenzene

There total 20 articles about 1-bromopropylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-Phenyl-1-propanol (93-54-9) → 1-bromopropylbenzene (2114-36-5,101308-38-7)

Guidance literature:

With phosphorus tribromide; In dichloromethane; at 20 ℃;

DOI:10.1080/00397910500290516

Reference yield: 92.0%

2-Phenylbutyric acid (90-27-7) → 1-bromopropylbenzene (2114-36-5,101308-38-7)

Guidance literature:

With silver triflate-bis(1,10-phenanthroline) complex; dibromoisocyanuric acid; In 1,2-dichloro-ethane; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.7b00439

Reference yield: 87.0%

1-phenylpropene (637-50-3) → 1-bromopropylbenzene (2114-36-5,101308-38-7)

Guidance literature:

With C₆H₁₂N₂O*BrH; at 20 ℃; for 10h;

DOI:10.1002/chem.201703457

upstream raw materials:

carbon tetrabromide

phenylpropane

cyclopropylbenzene

1-Phenyl-1-propanol

Downstream raw materials:

3-(α-ethylbenzyl)-6-phenethyl-4-hydroxy-2H-pyran-2-one

2-(3-methoxyphenyl)-5-phenylpentane

2-(3,5-dimethoxyphenyl)-5-phenylpentane

2-(2',5'-dimethoxyphenyl)-5-phenyl-2-pentene

Refernces

• 1、 Chen, Shuming,Gieuw, Matthew H.,Houk, K. N.,Ke, Zhihai,Yeung, Ying-Yeung. "Boron tribromide as a reagent for anti-Markovnikov addition of HBr to cyclopropanes". . p. 9426 - 9433. Retrieved 2020/10/02.
• 2、 -. "Method for synthesizing alkyne through catalytic asymmetric cross coupling (by machine translation)". Paragraph 0205-0212. . Retrieved 2020/01/12.