4-bromobenzyl 4-bromophenyl sulfide

Base Information

• Chemical Name: 4-bromobenzyl 4-bromophenyl sulfide
• CAS No.: 100398-19-4
• Molecular Formula: C13H10Br2S
• Molecular Weight: 358.096
• Mol file: 100398-19-4.mol

Synonyms:(4-Brom-benzyl)-(4-brom-phenyl)-sulfid;(4-bromo-benzyl)-(4-bromo-phenyl)-sulfide;

Chemical Property of 4-bromobenzyl 4-bromophenyl sulfide

Chemical Property:

• PSA: 25.30000
• LogP: 5.50390

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-bromobenzyl 4-bromophenyl sulfide

There total 3 articles about 4-bromobenzyl 4-bromophenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-bromo-4-(4-bromobenzylsulfinyl)benzene (100398-15-0) → (4-bromobenzyl)(4-bromophenyl)sulfane (100398-19-4)

Guidance literature:

With bromine; triphenylphosphine; copper(I) bromide; In acetonitrile; for 27h; Heating;

DOI:10.1246/cl.2007.1324

Reference yield:

4-bromothiophenol sodium salt (13457-82-4) + 1-bromomethyl-4-bromobenzene (589-15-1) → (4-bromobenzyl)(4-bromophenyl)sulfane (100398-19-4)

Guidance literature:

In acetone; at 50 ℃; for 3h;

DOI:10.1016/j.tet.2015.05.036

Reference yield:

→ (4-bromobenzyl)(4-bromophenyl)sulfane (100398-19-4)

Guidance literature:

With ethanol;

DOI:10.1017/S1092852900022045

upstream raw materials:

1-bromo-4-(4-bromobenzylsulfinyl)benzene

4-bromothiophenol sodium salt

1-bromomethyl-4-bromobenzene

Downstream raw materials:

1-bromo-4-(4-bromobenzylsulfinyl)benzene

4-bromobenzyl 4-bromophenyl sulfone

(4-dihydroxyborylphenyl)(4-dihydroxyborylbenzyl)sulfide

Refernces

• 1、 Capozzi, Maria Annunziata M.,Terraneo, Giancarlo,Cavallo, Gabriella,Cardellicchio, Cosimo. "The search for exceptions in the highly enantioselective titanium catalysed oxidation of aryl benzyl sulfides". . p. 4810 - 4816. Retrieved 2015/07/27.