Technology Process of [(η5-C5Me5)(CO)2W[κ2C,N-C(Et)=N(Si(p-Tol)3)]]
There total 2 articles about [(η5-C5Me5)(CO)2W[κ2C,N-C(Et)=N(Si(p-Tol)3)]] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
B(C6H5)3;
In
toluene;
byproducts: B(C6H5)3*CH3)2NC5H4N; (N2, glovebox) a toluene-soln. of complex and nitrile was allowed to satnd at room temp. for 1 d; B(C6H5)3 and hexane were added, the mixt. was stirred for 1 h, (CH3)2NC5H4N*B(C6H5)3 was filtered off, washed with hexane, the filtrate was evapd. under vac., recrystd. from hexane at -35°C; elem. anal.;
DOI:10.1021/om901123w
- Guidance literature:
-
In
toluene;
(N2, glovebox) a soln. of complex in toluene was added to solid HSi(C6H4CH3)3, the mixt. was allowed to stand at room temp. for 25 min; evapd. under vac., the residue was extd. with hexane, concd., cooled at -35°C; elem. anal.;
DOI:10.1021/om901123w
- Guidance literature:
-
In
(2)H8-toluene;
a Pyrex tube containing a soln. of complex in toluene-d8 was sealed under high-vac., heated at 120°C for 24 h; evapd. to dryness, allowed to stand for 1 d, washed with hexane; elem. anal.;
DOI:10.1021/om901123w
