Yb((CH₃)3SiNCC₆H₅NCH₂)2CH₂(NHC₆H₃(CH(CH₃)2)2C₆H₅CN)C₆H₅CN

Base Information

• Chemical Name: Yb((CH₃)3SiNCC₆H₅NCH₂)2CH₂(NHC₆H₃(CH(CH₃)2)2C₆H₅CN)C₆H₅CN
• CAS No.: 1386371-69-2
• Molecular Formula: C₄₉H₆₂N₇Si₂Yb
• Molecular Weight: 978.289
• Mol file: 1386371-69-2.mol

Synonyms:

Chemical Property of Yb((CH₃)3SiNCC₆H₅NCH₂)2CH₂(NHC₆H₃(CH(CH₃)2)2C₆H₅CN)C₆H₅CN

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Yb((CH₃)3SiNCC₆H₅NCH₂)2CH₂(NHC₆H₃(CH(CH₃)2)2C₆H₅CN)C₆H₅CN

There total 1 articles about Yb((CH₃)3SiNCC₆H₅NCH₂)2CH₂(NHC₆H₃(CH(CH₃)2)2C₆H₅CN)C₆H₅CN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

[Me3SiNC(Ph)N(CH2)3NC(Ph)NSiMe3]Yb(NH-2,6-(i)Pr2C6H3)(DME) (1000994-55-7) + benzonitrile (100-47-0) → Yb((CH3)3SiNCC6H5NCH2)2CH2(NHC6H3(CH(CH3)2)2C6H5CN)C6H5CN (1386371-69-2)

Guidance literature:

In toluene; (under Ar, Schlenk); Yb-complex dissolved in toluene, C6H5CN added understirring, stirred at 100°C for 12 h; solvent removed under reduced pressure, residue extd. with toluene, centrifuged, concd., crystd. from toluene at room temp. for several d; elem.anal.;

DOI:10.1039/c2dt30400g

Reference yield:

1,2-dimethoxyethane (110-71-4) + 2,6-diisopropylbenzenamine (24544-04-5) + Yb((CH3)3SiNCC6H5NCH2)2CH2(NHC6H3(CH(CH3)2)2C6H5CN)C6H5CN (1386371-69-2) → [Me3SiNC(Ph)N(CH2)3NC(Ph)NSiMe3]Yb(NH-2,6-(i)Pr2C6H3)(DME) (1000994-55-7)

Guidance literature:

In toluene; (under Ar, Schlenk); ligand added into toluene soln. of Yb-complex, stirred at 100°C for 12 h; solvent removed under reduced pressure, residue extd. with n-hexane, then with toluene, centrifuged, crystd. at -15°C for 3 d;

DOI:10.1039/c2dt30400g

upstream raw materials:

[Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃]Yb(NH-2,6-(i)Pr₂C₆H₃)(DME)

benzonitrile

Downstream raw materials:

[Me₃SiNC(Ph)N(CH₂)3NC(Ph)NSiMe₃]Yb(NH-2,6-(i)Pr₂C₆H₃)(DME)

Refernces