Benzenemethanol, 3-fluoro-, acetate

Base Information

• Chemical Name: Benzenemethanol, 3-fluoro-, acetate
• CAS No.: 102606-95-1
• Molecular Formula: C9H9FO2
• Molecular Weight: 168.168
• Mol file: 102606-95-1.mol

Synonyms:3-flourobenzyl acetate;

Chemical Property of Benzenemethanol, 3-fluoro-, acetate

Chemical Property:

• Boiling Point: 200.8±15.0 °C(Predicted)
• PSA: 26.30000
• Density: 1.148±0.06 g/cm3(Predicted)
• LogP: 1.88880

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenemethanol, 3-fluoro-, acetate

There total 4 articles about Benzenemethanol, 3-fluoro-, acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

3-fluoro-benzenemethanol (456-47-3) + acetic anhydride (108-24-7) → meta-fluorobenzyl acetate (102606-95-1)

Guidance literature:

With supported L-pyrrolidine-2-carboxylic acid-4-hydrogen sulfate on Silica Gel; at 20 ℃; for 3.75h; Green chemistry;

DOI:10.2174/1570178611310050004

Reference yield: 90.0%

3-fluoro-benzenemethanol (456-47-3) → meta-fluorobenzyl acetate (102606-95-1)

Guidance literature:

With phenyl-trimethyl-ammonium perbromide; In acetone; at 20 ℃; for 2h;

DOI:10.1134/S1070428013120026

Reference yield: 83.0%

3-fluoro-benzenemethanol (456-47-3) + acetic anhydride (108-24-7) → meta-fluorobenzyl acetate (102606-95-1) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

With 3-((3-(trisilyloxy)propyl)propionamide)-1-methylimidazolium chloride ionic liquid supported on magnetic nanoparticle Fe₂O₃; at 20 ℃; for 2.5h;

DOI:10.1016/j.jmmm.2015.10.044

upstream raw materials:

3-fluoro-benzenemethanol

acetyl chloride

acetic anhydride

Downstream raw materials:

3-fluoro-benzenemethanol

Refernces

• 1、 Ghorbani-Choghamarani,Shiri,Rostami. "Acetylation of alcohols with acetic anhydride promoted by N,N,N-trimethylanilinium tribromide". . p. 1728 - 1730. Retrieved 2013.
• 2、 Hajjami, Maryam,Ghorbani-Choghamarani, Arash,Karamshahi, Zahra,Norouzi, Masoomeh. "Tribromo melamine as novel and versatile catalyst for the formylation and acetylation of alcohols". . p. 260 - 263. Retrieved 2014/03/21.