Benzyl (2-methoxyethoxy)methyl selenide

Base Information

• Chemical Name: Benzyl (2-methoxyethoxy)methyl selenide
• CAS No.: 152407-20-0
• Molecular Formula: C₁₁H₁₆O₂Se
• Molecular Weight: 259.207
• Mol file: 152407-20-0.mol

Synonyms:

Chemical Property of Benzyl (2-methoxyethoxy)methyl selenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzyl (2-methoxyethoxy)methyl selenide

There total 1 articles about Benzyl (2-methoxyethoxy)methyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dibenzyl diselenide (1482-82-2) + 2-Methoxyethoxymethyl chloride (3970-21-6) → Benzyl (2-methoxyethoxy)methyl selenide (152407-20-0)

Guidance literature:

With lithium aluminium tetrahydride; Yield given. Multistep reaction; 1.) ether, -78 deg C, 30 min, 2.) ether, from -78 deg C to RT;

DOI:10.1248/cpb.41.1160

Reference yield: 39.0%

Benzyl (2-methoxyethoxy)methyl selenide (152407-20-0) → dibenzyl selenide (1842-38-2) + 1,1’-[methylenebis(selanylmethylene)]dibenzene (27976-47-2)

Guidance literature:

With titanium tetrachloride; In benzene; for 1.5h; Ambient temperature;

DOI:10.1021/jo00084a017

Reference yield:

Benzyl (2-methoxyethoxy)methyl selenide (152407-20-0) + toluene (108-88-3,15644-74-3,16713-13-6) → 1,1’-[methylenebis(selanylmethylene)]dibenzene (27976-47-2) + p-<(Benzylseleno)methyl>toluene + o-<(Benzylseleno)methyl>toluene

Guidance literature:

With titanium tetrachloride; for 1.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1021/jo00084a017

upstream raw materials:

dibenzyl diselenide

2-Methoxyethoxymethyl chloride

Downstream raw materials:

dibenzyl selenide

1,1’-[methylenebis(selanylmethylene)]dibenzene

Refernces