2,6-dibromoanisole-α-13C

Base Information

• Chemical Name: 2,6-dibromoanisole-α-13C
• CAS No.: 117923-78-1
• Molecular Formula: C₇H₆Br₂O
• Molecular Weight: 266.921
• Mol file: 117923-78-1.mol

Synonyms:

Chemical Property of 2,6-dibromoanisole-α-13C

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-dibromoanisole-α-13C

There total 2 articles about 2,6-dibromoanisole-α-13C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[13C]methyl iodide (4227-95-6) + 2,6-dibromophenol (608-33-3) → 2,6-dibromoanisole-α-13C (117923-78-1)

Guidance literature:

With potassium carbonate; In acetone;

Reference yield:

[13C]methyl iodide (4227-95-6) + 2,6-dibromoanisole (38603-09-7) → 2,6-dibromoanisole-α-13C (117923-78-1)

Guidance literature:

2,6-dibromoanisole; With boron tribromide; Inert atmosphere;

[13C]methyl iodide; With potassium carbonate;

DOI:10.1002/chem.201504780

Reference yield:

tributyltin chloride (1461-22-9) + 2,6-dibromoanisole-α-13C (117923-78-1) → C31H60OSn2 + 2-tri-n-butylstannylanisole (86487-17-4)

Guidance literature:

2,6-dibromoanisole-α-13C; With tert.-butyl lithium; Inert atmosphere;

tributyltin chloride; Inert atmosphere;

DOI:10.1002/chem.201504780

upstream raw materials:

[13C]methyl iodide

2,6-dibromophenol

2,6-dibromoanisole

Downstream raw materials:

2-tri-n-butylstannylanisole

Refernces

• 1、 Schaefer, Ted,Penner, Glenn H.. "Long-range 13C,13C spin-spin coupling constants in anisole and some derivatives". . p. 1635 - 1640. Retrieved 2007/10/02.