9-(METHYLAMINOMETHYL)ANTHRACENE

Base Information

• Chemical Name: 9-(METHYLAMINOMETHYL)ANTHRACENE
• CAS No.: 73356-19-1
• Molecular Formula: C16H15 N
• Molecular Weight: 221.302
• Hs Code.: 2921499090
• Mol file: 73356-19-1.mol

Synonyms:9-(N-Methylaminomethyl)anthracene;9-Methylaminomethylanthracene; N-Methyl-9-anthracenemethylamine

Chemical Property of 9-(METHYLAMINOMETHYL)ANTHRACENE

Chemical Property:

• Vapor Pressure: 2.82E-06mmHg at 25°C
• Melting Point: 57-59 °C(lit.)
• Boiling Point: 389.6°C at 760 mmHg
• PKA: 9.75±0.10(Predicted)
• Flash Point: 208.5°C
• PSA: 12.03000
• Density: 1.11g/cm³
• LogP: 4.10330
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

9-(N-Methylaminomethyl)anthracene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 9-(Methylaminomethyl)anthracene (MAMA) was used as a model drug in the study of the effect of enzymatic degradation on the release behaviors of MAMA by UV-Vis spectroscopy. It was also used as a reagent in a sensitive method for determination of isocyanates in air by HPLC via UV or fluorescence detection.

Technology Process of 9-(METHYLAMINOMETHYL)ANTHRACENE

There total 5 articles about 9-(METHYLAMINOMETHYL)ANTHRACENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

anthracenylmethyl chloride (24463-19-2) + methylamine (74-89-5) → 9-[(methylamino)methyl]anthracene (73356-19-1)

Guidance literature:

With potassium carbonate; potassium iodide; In methanol; N,N-dimethyl-formamide; at 20 ℃; for 3h;

DOI:10.1039/c3cc46824k

Reference yield: 38.0%

9-anthracene aldehyde (642-31-9) + methylamine (74-89-5) → 9-[(methylamino)methyl]anthracene (73356-19-1)

Guidance literature:

With hydrogen; platinum on activated charcoal; In methanol; water;

DOI:10.1021/jm00134a003

Reference yield:

9-anthracene aldehyde (642-31-9) → 9-[(methylamino)methyl]anthracene (73356-19-1)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran; methanol

2: NaBH₄

With sodium tetrahydroborate; In tetrahydrofuran; methanol;

DOI:10.1016/S0040-4039(03)00942-0

upstream raw materials:

9-anthracene aldehyde

methylamine

N-(9-anthrylmethylidene)methylamine

anthracenylmethyl chloride

Downstream raw materials:

(2-(((anthracen-9-ylmethyl)(methyl)amino)methyl)phenyl)boronic acid

1-(anthracen-9-yl)-N-methyl-N-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)methanamine

chlorodiphenyltin(IV) 9-(methylaminomethyl)-anthracenyl dithiocarbamate

C₂₃H₁₈INO

Refernces

• 1、 Arimori, Susumu,Consiglio, Giuseppe A.,Phillips, Marcus D.,James, Tony D.. "Tuning saccharide selectivity in modular fluorescent sensors". . p. 4789 - 4792. Retrieved 2007/10/03.