[((C₅H₄N)N=C(C₆H₅))RhHCl(PiPr₃)2]

Base Information

• Chemical Name: [((C₅H₄N)N=C(C₆H₅))RhHCl(PiPr₃)2]
• CAS No.: 756866-16-7
• Molecular Formula: C₃₀H₅₂ClN₂P₂Rh
• Molecular Weight: 641.062
• Mol file: 756866-16-7.mol

Synonyms:

Chemical Property of [((C₅H₄N)N=C(C₆H₅))RhHCl(PiPr₃)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((C₅H₄N)N=C(C₆H₅))RhHCl(PiPr₃)2]

There total 1 articles about [((C₅H₄N)N=C(C₆H₅))RhHCl(PiPr₃)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

2-(phenyliminomethyl)pyridine (7032-25-9) + chlorobis(cyclooctene)rhodium(I) dimer + tris(1-methylethyl)phosphine (6476-36-4) → [((C5H4N)N=C(C6H5))RhHCl(PiPr3)2] (756866-16-7)

Guidance literature:

In tetrahydrofuran; under Ar atm. soln. Rh complex and Schiff base in THF was treated with PiPr3 and stirred for 18 h at room temp.; soln. was concd. in vacuo and cooled to -20°C, pentane was added,ppt. was washed with pentane (-20°C) and dried; elem. anal.;

DOI:10.1016/j.ica.2003.12.018

Reference yield: 82.0%

[((C5H4N)N=C(C6H5))RhHCl(PiPr3)2] (756866-16-7) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → [((C5H4N)N=C(C6H5))RhHI(PiPr3)2] (756866-08-7)

Guidance literature:

In benzene; byproducts: NaCl; under Ar atm. soln. Rh complex in benzene was treated with NaI and stirred for 18 h at room temp.; react. mixt. was filtered and concd. in vacuo, pentane was added at -20°C, ppt. was washed with pentane (-20°C) and dried; elem. anal.;

DOI:10.1016/j.ica.2003.12.018

Reference yield: 81.0%

lithium aluminium tetrahydride (16853-85-3) + [((C5H4N)N=C(C6H5))RhHCl(PiPr3)2] (756866-16-7) → [((C5H4N)N=C(C6H5))RhH2(PiPr3)2] (756866-15-6)

Guidance literature:

In diethyl ether; under N2 atm. soln. Rh complex in Et2O was treated with LiAlH4 and stirred for 30 min at room temp.; solvent was evapd. in vacuo, residue was extd. with bentane, extract evapd. in vacuo;

DOI:10.1016/j.ica.2003.12.018

upstream raw materials:

2-(phenyliminomethyl)pyridine

tris(1-methylethyl)phosphine

Downstream raw materials:

[((C₅H₄N)N=C(C₆H₅))RhH(PiPr₃)2]PF₆

[((C₅H₄N)N=C(C₆H₅))RhH₂(PiPr₃)2]

[((C₅H₄N)N=C(C₆H₅))RhHI(PiPr₃)2]

[((C5H4N)N=C(C6H5))RhH(κ1-O3SCF3)(PiPr3)2]

Refernces