trans-[Ru(III)(C₆H₄CHNNC(4-Me-C₆H₄)O)(PPh₃)2Cl]

Base Information

• Chemical Name: trans-[Ru(III)(C₆H₄CHNNC(4-Me-C₆H₄)O)(PPh₃)2Cl]
• CAS No.: 928151-54-6
• Molecular Formula: C₅₁H₄₂ClN₂OP₂Ru
• Molecular Weight: 897.378
• Mol file: 928151-54-6.mol

Synonyms:

Chemical Property of trans-[Ru(III)(C₆H₄CHNNC(4-Me-C₆H₄)O)(PPh₃)2Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[Ru(III)(C₆H₄CHNNC(4-Me-C₆H₄)O)(PPh₃)2Cl]

There total 1 articles about trans-[Ru(III)(C₆H₄CHNNC(4-Me-C₆H₄)O)(PPh₃)2Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + C6H5CHNNC(C6H4CH3)OH (6958-43-6) → trans-[Ru(III)(C6H4CHNNC(4-Me-C6H4)O)(PPh3)2Cl] (928151-54-6)

Guidance literature:

With N(C₂H₅)3; In methanol; solid Ru complex was added to soln. of ligand and NEt3, mixt. was stirred at room temp. for 2 h; ppt. was filtered, washed with hexane, dissolved in CH2Cl2/MeCN (1:6) mixt., hexane was added to this soln. and left in air for slow evapn., crystals were sepd. in about 2 d, dried in air; elem. anal.;

DOI:10.1016/j.jorganchem.2006.10.026

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

C₆H₅CHNNC(C₆H₄CH₃)OH

Refernces